Recent advances in heterocyclic nanographenes and other polycyclic heteroaromatic compounds

A Borissov, YK Maurya, L Moshniaha… - Chemical …, 2021 - ACS Publications
This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …

Recent advances in supramolecular fullerene chemistry

X Chang, Y Xu, M von Delius - Chemical Society Reviews, 2023 - pubs.rsc.org
Fullerene chemistry has come a long way since 1990, when the first bulk production of C60
was reported. In the past decade, progress in supramolecular chemistry has opened some …

Selective Encapsulation and Chiral Induction of C60 and C70 Fullerenes by Axially Chiral Porous Aromatic Cages

J Kou, Q Wu, D Cui, Y Geng, K Zhang… - Angewandte …, 2023 - Wiley Online Library
Chiral induction has been an important topic in chemistry, not only for its relevance in
understanding the mysterious phenomenon of spontaneous symmetry breaking in nature …

Pd (II) coordination sphere engineering: pyridine cages, quinoline bowls, and heteroleptic pills binding one or two fullerenes

B Chen, JJ Holstein, S Horiuchi, WG Hiller… - Journal of the …, 2019 - ACS Publications
Fullerenes and their derivatives are of tremendous technological relevance. Synthetic
access and application are still hampered by tedious purification protocols, peculiar …

Nitrogen-embedded quintuple [7] helicene: a helicene–azacorannulene hybrid with strong near-infrared fluorescence

YF Wu, SW Ying, LY Su, JJ Du, L Zhang… - Journal of the …, 2022 - ACS Publications
Herein, a nitrogen-embedded quintuple [7] helicene (N-Q7H) with an
azapentabenzocorannulene core, which can be considered to be a helicene …

Facile Synthesis of Nitrogen‐Doped Nanographenes with Joined Nonhexagons via a Ring Expansion Strategy

H Luo, J Liu - Angewandte Chemie, 2023 - Wiley Online Library
Synthetic methodology is considered a holy grail in both organic chemistry and materials
science. Over the past few decades, researchers have explored graphene‐type molecules …

Bowl‐Shaped Pentagon‐ and Heptagon‐Embedded Nanographene Containing a Central Pyrrolo[3,2‐b]pyrrole Core

M Krzeszewski, Ł Dobrzycki, AL Sobolewski… - Angewandte …, 2021 - Wiley Online Library
A bowl‐shaped nitrogen‐doped nanographene composed of a pyrrolo [3, 2‐b] pyrrole core
substituted with six arene rings circularly bonded with one another has been prepared via a …

Self-Assembled Perylene Bisimide-Cored Trigonal Prism as an Electron-Deficient Host for C60 and C70 Driven by “Like Dissolves Like”

X Chang, S Lin, G Wang, C Shang… - Journal of the …, 2020 - ACS Publications
Poor processability of fullerenes is a major remaining drawback for them to be studied
monomolecularly and to find real-life applications. One of the strategies to tackle this …

Micromolar Affinity and Higher: Synthetic Host–Guest Complexes with High Stabilities

S Sarkar, P Ballester, M Spektor… - Angewandte Chemie …, 2023 - Wiley Online Library
The design of high‐affinity synthetic host–guest complexes is of paramount importance
because they are key elements in constructing unprecedented supramolecular assemblies …

Heptagon‐Containing Nanographene Embedded into [10] Cycloparaphenylene

JP Mora‐Fuentes, MD Codesal, M Reale… - Angewandte Chemie …, 2023 - Wiley Online Library
We report the synthesis and characterization of a novel type of nanohoop, consisting of a
cycloparaphenylene derivative incorporating a curved heptagon‐containing π‐extended …