Recent advances in heterogeneous hydrosilylation of unsaturated carbon-carbon bonds

H Yang, Z Zhou, C Tang, F Chen - Chinese Chemical Letters, 2024 - Elsevier
The hydrosilylation of unsaturated carbon-carbon bonds is one of the most critical reactions
in silicone industrial production. The homogeneous Speier's catalyst, Karstedt's catalyst, and …

σ-H–H, σ-C–H, and σ-Si–H bond activation catalyzed by metal nanoparticles

JM Asensio, D Bouzouita, PWNM van Leeuwen… - Chemical …, 2019 - ACS Publications
Activation of H–H, Si–H, and C–H bonds through σ-bond coordination has grown in the past
30 years from a scientific curiosity to an important tool in the functionalization of …

Discovering partially charged single-atom Pt for enhanced anti-Markovnikov alkene hydrosilylation

Y Chen, S Ji, W Sun, W Chen, J Dong… - Journal of the …, 2018 - ACS Publications
The hydrosilylation reaction is one of the largest-scale application of homogeneous catalysis
and is widely used to enable the commercial manufacture of silicon products. However …

Supported palladium–gold alloy catalysts for efficient and selective hydrosilylation under mild conditions with isolated single palladium atoms in alloy nanoparticles as …

H Miura, K Endo, R Ogawa, T Shishido - ACS Catalysis, 2017 - ACS Publications
Supported Pd–Au alloy catalysts were developed for the highly efficient and selective
hydrosilylation of α, β-unsaturated ketones and alkynes. The Pd/Au atomic ratio of the Pd …

Evidence for the “cocktail” nature of platinum-catalyzed alkyne and alkene hydrosilylation reactions

EE Ondar, JV Burykina, VP Ananikov - Catalysis Science & Technology, 2022 - pubs.rsc.org
Evidence of the involvement of a “cocktail”-type catalytic system in the alkyne and alkene
hydrosilylation reaction in the presence of platinum on a carbon support is reported. The …

Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts

JC Gee, BA Fuller, HM Lockett, G Sedghi… - Chemical …, 2018 - pubs.rsc.org
Platinum–[diaminocarbene] complexes work as transition-metal photocatalysts for the
hydrosilylation of alkynes. A catalytic system operates under visible light irradiation (blue …

Impregnated platinum on magnetite as an efficient, fast, and recyclable catalyst for the hydrosilylation of alkynes

R Cano, M Yus, DJ Ramon - ACS Catalysis, 2012 - ACS Publications
New impregnated platinum on magnetite catalyst has been prepared, characterized and
used for the hydrosilylation of different alkynes. The catalyst showed a wide reaction scope …

Metal-organic frameworks-derived nitrogen-doped carbon supported nanostructured PtNi catalyst for enhanced hydrosilylation of 1-octene

J Wen, Y Chen, S Ji, J Zhang, D Wang, Y Li - Nano Research, 2019 - Springer
Here, we successfully developed nanostructured PtNi particles supported on nitrogen-
doped carbon (NC), which were obtained by carbonization of metal-organic frameworks …

Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part I

IP Beletskaya, C Nájera, M Yus - Russian Chemical Reviews, 2020 - iopscience.iop.org
The review presents state-of-the-art data on the influence of catalysts (mainly transition
metal complexes) on the regioselectivity of a number of reactions. The most important …

Regio-and stereoselective hydrosilylation of alkynes catalyzed by SiO 2 supported Pd–Cu bimetallic nanoparticles

J Zhang, G Lu, C Cai - Green Chemistry, 2017 - pubs.rsc.org
An efficient, recyclable Pd–Cu bimetallic nanoparticle catalyst has been prepared, which
exhibits superior activity and selectivity toward the hydrosilylation of internal and terminal …