A variety of Pd‐catalyzed reactions are carried out with palladium carboxylates in the
presence of carboxylic acids and/or alkali metal carboxylates. This review is Part A of three …

Transition‐metal‐catalyzed decarboxylative cross‐coupling reaction provides a powerful
method for the construction C− C, C− N, C− O bonds, which have great impact on synthetic …

Backbone-enabled site-selective modification of peptides with benzoquinone via Pd-
catalyzed δ-C (sp2)–H functionalization has been achieved. The amide groups of peptides …

Abstract A rhodium (III)‐catalyzed C− H activation/[4+ 1] annulation of 2‐aryl‐3H‐indoles
and CF3‐substituted imidoyl sulfoxonium ylides (TFISYs) has been achieved, producing a …

We herein describe the high-valent cobalt-catalyzed C (sp3)–H functionalization of amide
derivatives with silver acetylides generated in situ. The reaction proceeds under kinetic …

Chemical transformations involving the pyrenylglycine motif (an unnatural amino acid) and
practical methods toward it are seldom known. This work aimed at developing a method for …

Menadione and its structural analogues are important motifs present in various bioactive
natural products and drugs with a wide range of biological activities. In addition, β …

Limonene undergoes a regioselective Pd (II)-catalyzed C (sp2)–H/C (sp2)–H coupling with
acrylic acid esters and amides, α, β-unsaturated ketones, styrenes, and allyl acetate …

In this work, we present a design concept of introducing linear structures into the orthogonal
configuration of 9, 9'-spirobifluorene (SBF), aiming to enhance carrier mobilities while …

This paper reports the construction of racemic and enantiopure (D‐and L‐) fluorene and
fluorenone‐based novel unnatural amino acid derivatives. The Pd (II)‐catalyzed bidentate …