Mixed self-assembly of ligands 1, 2, 1, 6-hexanediamine (HDA), and Pd (NO3) 2 afforded
Fujita-type metal organic polyhedron MOP1 (diameter≈ 8.2 nm), which is covalently …

A water‐soluble Pd6 trigonal prism (A) was synthesized by two‐component coordination‐
driven self‐assembly of a PdII 90° acceptor with a tetraimidazole donor. The walls of the …

Covalent post-assembly modification (PAM) reactions are useful synthetic tools for
functionalizing and stabilizing self-assembled metal–organic complexes. Recently, PAM …

Self‐assembled cages have garnered wide‐spread interest as supramolecular hosts. Their
abilities may be augmented through the installation of functional groups on the interior of the …

In this frontier article we highlight recent advances in subcomponent self-sorting in self-
assembled metal–ligand cage complexes, with a focus on selective discrimination between …

We have prepared a series of MII 4L6 tetrahedral cages containing one or the other of two
distinct BODIPY moieties, as well as mixed cages that contain both BODIPY chromophores …

A major hurdle in the development of complex constitutional dynamic networks (CDNs) is
the lack of strategies to simultaneously control the output of two (or more) interconnected …

This review describes the control of guest binding behavior of metal-containing host
molecules that is driven by ligand exchange reactions at the metal centers. Recently, a vast …

A series of discrete molecular architectures was synthesized via self-assembly of two “linear”
diimidazole donors [L1= 1, 4-di (1 H-imidazol-1-yl) benzene and L2= 1, 1′-(2, 5-dimethyl-1 …

This Account describes our efforts over the last decade to synthesize self-assembled metal–
ligand cage complexes that display reactive functional groups on their interiors. This journey …