As one of the effective strategies for carbohydrate synthesis, chemical synthesis can
precisely control the structure of sugar chains, thus establishing the structure-activity …

Pd‐catalyzed stereoselective glycosylations using unsaturated sugar derivatives, glycals,
have been successfully achieved in recent years. This review focuses on approaches to …

An efficient and practical glycosylation platform for synthesizing N-glycosides by leveraging
palladium catalysis is disclosed. This approach enables facile access to diverse heterocyclic …

Described here is a selective synthesis of 2, 3-dihydropyrrole-fused N-glycosides through
rhodium-catalyzed denitrogenative transannulation of N-sulfonyl-1, 2, 3-triazoles with …

Previous N‐glycosylation approaches have predominately involved acidic conditions, facing
challenges of low stereoselectivity and limited scope. Herein, we introduce a radical …

In this study, we report an organocatalytic formal coupling strategy for aryl-naphthoquinones
with thiosugars that provides straightforward access to the axially chiral naphthoquinone …

A one‐pot synthesis of 2, 3, 4‐unprotected β‐N‐glycopyranosides from glycals and amines
with exclusive β‐stereoselectivity under room temperature conditions is reported. This …

Despite the increased importance of C-glycosides in biochemistry, the strategy for creating
the C-glycosidic bond stereoselectively has received less attention than that for its O-and N …

Ferrier rearrangement on glycals is an efficient tool to form 2, 3-dideoxy glycosides that
provide access to various sugar derivatives through olefin functionalization. The classical …

A highly efficient, palladium-catalyzed glycosylation between 3, 4-O-carbonate glycals and
acid-labile oximes is disclosed. This approach features broad substrate scope, high …