We study the phase behavior and structure of highly asymmetric binary hard-sphere mixtures. By first integrating out the degrees of freedom of the small spheres in the partition …
S Zhou, JR Solana - Chemical reviews, 2009 - ACS Publications
Since the formulation of the so-called high temperature series expansion (HTSE) by Zwanzig, 1 thermodynamic perturbation theories developed along this line have been one of …
A Santos - Lecture Notes in Physics, 2016 - Springer
There exist in the market many excellent textbooks covering equilibrium statistical mechanics of liquids and dense gases. Why, then, yet another addition to the shelf? Is there …
A simple recipe to derive the compressibility factor of a multicomponent mixture of d- dimensional additive hard spheres in terms of that of the one-component system is …
Techniques to adapt the hit-and-miss Monte-Carlo numerical integration are proposed with the aim to determine virial coefficients up to eighth order in fluids of hard convex bodies …
A study of the binary hard-sphere fluid with size ratio [sgrave] B/[sgrave] A= 0.1 is reported. Molecular dynamics and Monte Carlo simulations have been carried out over the mole …
DJ Ashton, NB Wilding - The Journal of chemical physics, 2014 - pubs.aip.org
A simulation technique is described for quantifying the contribution of three-body interactions to the thermodynamical properties of coarse-grained representations of complex …
The composition-independent virial coefficients of ad-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the …
New calculations of the fifth virial coefficient are presented for binary hard sphere mixtures. These improve on, and in some cases correct, previous results. A polynomial fit is used to …