The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Sulfones are versatile intermediates in organic synthesis and important building blocks in
the construction of biological active molecules or functional materials. This review provides a …

Development of the methodology for the preparation of vinyl sulfones is of significant interest
to organic chemists. Recently, numerous useful methods have been developed, mainly …

Vinyl sulfones are important structural motifs with a wide range of applications in the
biomedical field. Although the hydrosulfonylations of alkynes have provided straightforward …

Azides are building blocks of increasing importance in synthetic chemistry, chemical biology,
and materials science. Azidobenziodoxolone (ABX, Zhdankin reagent) is a valuable azide …

While sulfonyl hydrazides are widely utilized in organic synthesis, it is only in recent years
that they have emerged as powerful sulfonyl sources. The hydrazinyl group can be readily …

A regioselective formation of C–S bonds has been achieved using a cross dehydrogenative
coupling (CDC) protocol using iodine as a catalyst and dimethyl sulfoxide as an oxidant …

A rhodium‐catalyzed anti‐Markovnikov hydroiodination of aromatic and aliphatic terminal
alkynes is reported. Depending on the choice of ligand and substrate, either (E)‐or (Z) …

This review is focused on the recent developments in transition‐metal‐free transformations
using N‐tosylhydrazones, emerging building blocks in contemporary organic chemistry …

The combination of well-defined Fe3+ isolated single-metal atoms and Ag2 subnanometer
metal clusters within the channels of a metal–organic framework (MOF) is reported and …