Li-rich cathodes for rechargeable Li-based batteries: reaction mechanisms and advanced characterization techniques
Due to their high specific capacities beyond 250 mA hg− 1, lithium-rich oxides have been
considered as promising cathodes for the next generation power batteries, bridging the …
considered as promising cathodes for the next generation power batteries, bridging the …
The role of O2 in O-redox cathodes for Li-ion batteries
The energy density of Li-ion batteries can be improved by storing charge at high voltages
through the oxidation of oxide ions in the cathode material. However, oxidation of O2 …
through the oxidation of oxide ions in the cathode material. However, oxidation of O2 …
Unlocking anionic redox activity in O3-type sodium 3d layered oxides via Li substitution
Sodium ion batteries, because of their sustainability attributes, could be an attractive
alternative to Li-ion technology for specific applications. However, it remains challenging to …
alternative to Li-ion technology for specific applications. However, it remains challenging to …
Surface regulation enables high stability of single-crystal lithium-ion cathodes at high voltage
Single-crystal cathode materials for lithium-ion batteries have attracted increasing interest in
providing greater capacity retention than their polycrystalline counterparts. However, after …
providing greater capacity retention than their polycrystalline counterparts. However, after …
Correlating ligand-to-metal charge transfer with voltage hysteresis in a Li-rich rock-salt compound exhibiting anionic redox
Anionic redox is a double-edged sword for Li-ion cathodes because it offers a
transformational increase in energy density that is also negated by several detrimental …
transformational increase in energy density that is also negated by several detrimental …
Capturing dynamic ligand-to-metal charge transfer with a long-lived cationic intermediate for anionic redox
Reversible anionic redox reactions represent a transformational change for creating
advanced high-energy-density positive-electrode materials for lithium-ion batteries. The …
advanced high-energy-density positive-electrode materials for lithium-ion batteries. The …
Dielectric Polarization in Inverse Spinel‐Structured Mg2TiO4 Coating to Suppress Oxygen Evolution of Li‐Rich Cathode Materials
High‐energy Li‐rich layered cathode materials (≈ 900 Wh kg− 1) suffer from severe
capacity and voltage decay during cycling, which is associated with layered‐to‐spinel phase …
capacity and voltage decay during cycling, which is associated with layered‐to‐spinel phase …
Transition metal migration and O2 formation underpin voltage hysteresis in oxygen-redox disordered rocksalt cathodes
Lithium-rich disordered rocksalt cathodes display high capacities arising from redox
chemistry on both transition-metal ions (TM-redox) and oxygen ions (O-redox), making them …
chemistry on both transition-metal ions (TM-redox) and oxygen ions (O-redox), making them …
Demystifying the lattice oxygen redox in layered oxide cathode materials of lithium-ion batteries
The practical application of lithium-ion batteries suffers from low energy density and the
struggle to satisfy the ever-growing requirements of the energy-storage Internet. Therefore …
struggle to satisfy the ever-growing requirements of the energy-storage Internet. Therefore …
Probing the Mysterious Behavior of Tungsten as a Dopant Inside Pristine Cobalt‐Free Nickel‐Rich Cathode Materials
Nickel‐rich cathode materials with small amounts of tungsten (W) dopants have attracted
extensive attention in recent years. However, the chemical state, crystalline form, compound …
extensive attention in recent years. However, the chemical state, crystalline form, compound …