Coordinative Chain Transfer and chain shuttling polymerization

R Mundil, C Bravo, N Merle, P Zinck - Chemical Reviews, 2023 - ACS Publications
Coordinative chain transfer polymerization, CCTP, is a degenerative chain transfer
polymerization process that has a wide range of applications. It allows a highly controlled …

Recent advances on the structure–properties relationship of multiblock copolymers

GP Baeza - Journal of Polymer Science, 2021 - Wiley Online Library
Multiblock copolymers represent a fascinating class of materials that sits at the very heart of
industrial applications and fundamental polymer science. They are most often made of a …

Extending the high-throughput experimentation (HTE) approach to catalytic olefin polymerizations: From catalysts to materials

A Vittoria, G Urciuoli, S Costanzo, D Tammaro… - …, 2022 - ACS Publications
In this study, a state-of-the-art high-throughput experimentation (HTE) workflow for catalytic
olefin polymerization, covering an unprecedented wide part of the polymer knowledge and …

In-depth analysis of the nonuniform chain microstructure of multiblock copolymers from chain-shuttling polymerization

G Urciuoli, A Vittoria, G Talarico, D Luise… - …, 2021 - ACS Publications
The nonuniform molecular architecture of ethylene/1-octene multiblock copolymers (O-
MBCs) synthesized by the chain shuttling technology is investigated. The samples consist of …

Thermal fractionation of ethylene/1-octene multiblock copolymers from chain shuttling polymerization

G Urciuoli, O Ruiz de Ballesteros, R Cipullo… - …, 2022 - ACS Publications
Ethylene/1-octene statistical multiblock copolymers (OMBCs) consisting of the alternation of
crystalline, hard blocks and amorphous, soft blocks, with≈ 0.5 and 20 mol% of 1-octene …

Model of crystallization behavior of isotactic polypropylene: The role of defects

M Scoti, F De Stefano, R Di Girolamo… - Macromolecular …, 2023 - Wiley Online Library
The crystallization behavior of propene–ethylene (iPPC2), propene–butene (iPPC4),
propene–pentene (iPPC5), and propene–hexene (iPPC6) isotactic copolymers, prepared …

Synthesis of Statistical Multiblock Copolymers through Chain Shuttling Copolymerization with a Thermomechanical Switch Behavior

A Vittoria, G Urciuoli, S Costanzo, V Ianniello… - …, 2024 - ACS Publications
A high-throughput experimentation (HTE) approach is adopted for the synthesis of a special
class of elastomeric polyolefins with a tailored thermomechanical response …

Crystallization, structure and properties of PP-b-PE block copolymer

X Hua, J Cheng, Y Wang, LZ Liu, Y Wang, Y Shi - Polymer, 2023 - Elsevier
In recent years, a commercialized polypropylene (PP) and polyethylene (PE) block
copolymer has been synthesized using chain-shuttling polymerization, but its molecular …

Molecular Architecture of Multiblock Copolymers Synthesized by the Chain Shuttling Technology

G Urciuoli, O Ruiz de Ballesteros… - … Chemistry and Physics, 2023 - Wiley Online Library
Recent advances in the characterization of ethylene/1‐octene‐based statistical multiblock
copolymers (MBCs) synthesized via chain shuttling copolymerization are illustrated. The …

Crystallization Kinetics of Crystalline–Crystalline and Crystalline–Amorphous Block Copolymers of Linear Polyethylene and Isotactic Polypropylene

A Cicolella, M Scoti, G Talarico, AJ Müller… - …, 2024 - ACS Publications
Crystalline–amorphous diblock copolymers (BCPs) comprising crystalline blocks of isotactic
polypropylene (iPP) or polyethylene (PE) linked to amorphous blocks of random ethylene …