Aromatics and cyclic molecules in molecular clouds: A new dimension of interstellar organic chemistry

MC McCarthy, BA McGuire - The Journal of Physical Chemistry A, 2021 - ACS Publications
Astrochemistry lies at the nexus of astronomy, chemistry, and molecular physics. On the
basis of precise laboratory data, a rich collection of more than 200 familiar and exotic …

Detection of two interstellar polycyclic aromatic hydrocarbons via spectral matched filtering

BA McGuire, RA Loomis, AM Burkhardt, KLK Lee… - Science, 2021 - science.org
Unidentified infrared emission bands are ubiquitous in many astronomical sources. These
bands are widely, if not unanimously, attributed to collective emissions from polycyclic …

Discovery of the pure polycyclic aromatic hydrocarbon indene (c-C9H8) with GOTHAM observations of TMC-1

AM Burkhardt, KLK Lee, PB Changala… - The Astrophysical …, 2021 - iopscience.iop.org
Polycyclic aromatic hydrocarbons (PAHs) have long been invoked in the study of interstellar
and protostellar sources, but the unambiguous identification of any individual PAH has …

Interstellar detection of the highly polar five-membered ring cyanocyclopentadiene

MC McCarthy, KLK Lee, RA Loomis, AM Burkhardt… - Nature …, 2021 - nature.com
Much like six-membered rings, five-membered rings are ubiquitous in organic chemistry,
frequently serving as the building blocks for larger molecules, including many of biochemical …

Discovery of interstellar 2-cyanoindene (2-C9H7CN) in GOTHAM observations of TMC-1

ML Sita, PB Changala, C Xue… - The Astrophysical …, 2022 - iopscience.iop.org
We present laboratory rotational spectroscopy of five isomers of cyanoindene (2-, 4-, 5-, 6-,
and 7-cyanoindene) using a cavity Fourier transform microwave spectrometer operating …

Discovery of two isomers of ethynyl cyclopentadiene in TMC-1: Abundances of CCH and CN derivatives of hydrocarbon cycles

J Cernicharo, M Agúndez, RI Kaiser… - Astronomy & …, 2021 - aanda.org
We report the detection of two isomers of ethynyl cyclopentadiene (cC 5 H 5 CCH), namely 1-
and 2-ethynyl-1, 3-cyclopentadiene, in the direction of TMC-1. We derive column densities of …

Detection of interstellar 1-cyanopyrene: A four-ring polycyclic aromatic hydrocarbon

G Wenzel, IR Cooke, PB Changala, EA Bergin… - Science, 2024 - science.org
Polycyclic aromatic hydrocarbons (PAHs) are organic molecules containing adjacent
aromatic rings. Infrared emission bands show that PAHs are abundant in space, but only a …

Early science from GOTHAM: Project overview, methods, and the detection of interstellar propargyl cyanide (HCCCH2CN) in TMC-1

BA McGuire, AM Burkhardt, RA Loomis… - The Astrophysical …, 2020 - iopscience.iop.org
We present an overview of the GBT Observations of TMC-1: Hunting Aromatic Molecules
Large Program on the Green Bank Telescope. This and a related program were launched to …

Interstellar detection of 2-cyanocyclopentadiene, C5H5CN, a second five-membered ring toward TMC-1

KLK Lee, PB Changala, RA Loomis… - The Astrophysical …, 2021 - iopscience.iop.org
Using radio observations with the Green Bank Telescope, evidence has now been found for
a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based …

Detections of interstellar aromatic nitriles 2-cyanopyrene and 4-cyanopyrene in TMC-1

G Wenzel, TH Speak, PB Changala, RHJ Willis… - Nature …, 2024 - nature.com
Polycyclic aromatic hydrocarbons (PAHs) are among the most widespread compounds in
the universe, accounting for up to~ 25% of all interstellar carbon. Since most unsubstituted …