Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications

J Zhang, Y Huang, G Li, Y Wei - Coordination Chemistry Reviews, 2019 - Elsevier
Polyoxometalates (POMs), an exceptional family of coordination clusters consisting of Mo,
W, V, etc. early transition metal ions in their highest oxidation states, have received …

Solution behaviors and self-assembly of polyoxometalates as models of macroions and amphiphilic polyoxometalate–organic hybrids as novel surfactants

P Yin, D Li, T Liu - Chemical Society Reviews, 2012 - pubs.rsc.org
Large, hydrophilic polyoxoanions with high solubility in water and/or other polar solvents
demonstrate unique solution behavior by self-assembling into single layer, hollow, spherical …

Ionic complexes of metal oxide clusters for versatile self-assemblies

B Li, W Li, H Li, L Wu - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus The combination of rational design of building components and suitable
utilization of driving force affords spontaneous molecular assemblies with well-defined …

Recent advances in RAFT-mediated surfactant-free emulsion polymerization

J Zhou, H Yao, J Ma - Polymer Chemistry, 2018 - pubs.rsc.org
Advances in the understanding and application of reversible addition–fragmentation chain
transfer (RAFT) polymerization in surfactant-free emulsion systems have been made over …

[HTML][HTML] Overview of Wells-Dawson Polyoxometalates: from structure and functionalization to application

D Nowicka, N Vadra, E Wieczorek-Szweda… - Coordination Chemistry …, 2024 - Elsevier
Abstract Wells-Dawson polyoxometalates (WD POMs) are an important subgroup within the
diverse family of POMs. In the last two decades, there has been remarkable progress in the …

Bioorthogonal chemistry of polyoxometalates–challenges and prospects

SK Petrovskii, EV Grachova, KY Monakhov - Chemical Science, 2024 - pubs.rsc.org
Bioorthogonal chemistry has enabled scientists to carry out controlled chemical processes in
high yields in vivo while minimizing hazardous effects. Its extension to the field of …

Crystal Structures and Proton Conductivities of a MOF and Two POM–MOF Composites Based on CuII Ions and 2,2′‐Bipyridyl‐3,3′‐dicarboxylic Acid

M Wei, X Wang, X Duan - Chemistry–A European Journal, 2013 - Wiley Online Library
We have succeeded in constructing a metal–organic framework (MOF),[Cu (bpdc)(H2O) 2] n
(H2bpdc= 2, 2′‐bipyridyl‐3, 3′‐dicarboxylic acid, 1), and two poly‐POM–MOFs (POM …

Multinuclear diffusion NMR spectroscopy and DFT modeling: A powerful combination for unraveling the mechanism of phosphoester bond hydrolysis catalyzed by …

TKN Luong, P Shestakova, TT Mihaylov… - … A European Journal, 2015 - Wiley Online Library
A detailed reaction mechanism is proposed for the hydrolysis of the phosphoester bonds in
the DNA model substrate bis (4‐nitrophenyl) phosphate (BNPP) in the presence of the ZrIV …

Side Group of Hydrophobic Amino Acids Controls Chiral Discrimination among Chiral Counterions and Metal–Organic Cages

E Raee, B Liu, Y Yang, T Namani, Y Cui, N Sahai… - Nano Letters, 2022 - ACS Publications
The self-assembly of chiral Pd12L24 metal–organic cages (MOCs) based on hydrophobic
amino acids, including alanine (Ala), valine (Val), and leucine (Leu), into single-layered …

Light‐and Solvent‐Controlled Self‐Assembly Behavior of Spiropyran–Polyoxometalate–Alkyl Hybrid Molecules

Y Chu, A Saad, P Yin, J Wu, O Oms… - … A European Journal, 2016 - Wiley Online Library
A molecular photochromic spiropyran–polyoxometalate–alkyl organic–inorganic hybrid has
been synthesized and fully characterized. The reversible switching of the hydrophobic …