Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Enantioselective radical reactions using chiral catalysts

S Mondal, F Dumur, D Gigmes, MP Sibi… - Chemical …, 2022 - ACS Publications
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Chiral photocatalyst structures in asymmetric photochemical synthesis

MJ Genzink, JB Kidd, WB Swords, TP Yoon - Chemical reviews, 2021 - ACS Publications
Asymmetric catalysis is a major theme of research in contemporary synthetic organic
chemistry. The discovery of general strategies for highly enantioselective photochemical …

Metal stereogenicity in asymmetric transition metal catalysis

PS Steinlandt, L Zhang, E Meggers - Chemical Reviews, 2023 - ACS Publications
Chiral transition metal catalysts represent a powerful and economic tool for implementing
stereocenters in organic synthesis, with the metal center providing a strong chemical …

Visible light-driven radical-mediated C–C bond cleavage/functionalization in organic synthesis

XY Yu, JR Chen, WJ Xiao - Chemical Reviews, 2020 - ACS Publications
Thermal C–C bond cleavage reactions allow the construction of structurally diverse
molecular skeletons via predictable and efficient bond reorganizations. Visible light …

Hantzsch esters: an emerging versatile class of reagents in photoredox catalyzed organic synthesis

PZ Wang, JR Chen, WJ Xiao - Organic & Biomolecular Chemistry, 2019 - pubs.rsc.org
Hantzsch esters were often previously used as reductants in thermal catalytic hydrogenation
reactions. Over the last few decades, Hantzsch esters have proven to be a useful class of …

Enantioselective radical addition to ketones through Lewis acid-enabled photoredox catalysis

L Hou, Y Zhou, H Yu, T Zhan, W Cao… - Journal of the American …, 2022 - ACS Publications
Photocatalysis opens up a new window for carbonyl chemistry. Despite a multitude of
photochemical reactions of carbonyl compounds, visible light-induced catalytic asymmetric …

Asymmetric photocatalysis with bis-cyclometalated rhodium complexes

X Huang, E Meggers - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus Aspects of sustainability are playing an increasingly important role for the
development of new synthetic methods. In this context, the combination of asymmetric …

Combined photoredox and carbene catalysis for the synthesis of ketones from carboxylic acids

AV Bay, KP Fitzpatrick, RC Betori… - Angewandte …, 2020 - Wiley Online Library
As a key element in the construction of complex organic scaffolds, the formation of C− C
bonds remains a challenge in the field of synthetic organic chemistry. Recent advancements …

Recent advances in radical chemistry proceeding through pro-aromatic radicals

A Bhunia, A Studer - Chem, 2021 - cell.com
This review illustrates pioneering work and recent advancements on the use of pro-aromatic
compounds as carbon-and heteroatom-radical precursors. Pro-aromatic systems such as 1 …