Material research from the viewpoint of functional motifs

XM Jiang, S Deng, MH Whangbo… - National Science …, 2022 - academic.oup.com
As early as 2001, the need for the 'functional motif theory'was pointed out, to assist the
rational design of functional materials. The properties of materials are determined by their …

Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

Y Shang, J Xu, H Sha, Z Wang, C He, R Su… - Coordination Chemistry …, 2023 - Elsevier
Nonlinear optical (NLO) crystals are an essential support for laser applications, as they
could extend the tunable range of all-solid-state lasers. NLO inorganic sulfates always …

Guanidinium fluorooxoborates as efficient metal-free short-wavelength nonlinear optical crystals

C Jin, H Zeng, F Zhang, H Qiu, Z Yang… - Chemistry of …, 2021 - ACS Publications
Metal-free borates have emerged as a new class of solid-state chemistry and related
crystalline materials with high performance. However, the discovery of metal-free borate …

Discovery of First Magnesium Fluorooxoborate with Stable Fluorine Terminated Framework for Deep‐UV Nonlinear Optical Application

M Xia, F Li, M Mutailipu, S Han, Z Yang… - Angewandte …, 2021 - Wiley Online Library
The generated light can be tuned to cover almost the entire spectral range from deep‐
ultraviolet to terahertz wavelengths by utilizing the nonlinear optical crystals with a simple …

Giant Mid‐Infrared Second‐Harmonic Generation Response in a Densely‐Stacked Van Der Waals Transition‐Metal Oxychloride

C Jin, X Jiang, C Wu, K Duanmu, Z Lin… - Angewandte …, 2023 - Wiley Online Library
Second‐harmonic generation (SHG) is a fundamental optical property of nonlinear optical
(NLO) crystals. Thus far, it has proved difficult to engineer large SHG responses, particularly …

Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis-[Zr 6 F 34] 10− clusters

M Yan, RL Tang, WD Yao, W Liu, SP Guo - Chemical Science, 2024 - pubs.rsc.org
Traditional fluorides are rarely reported as candidates for nonlinear optical (NLO) materials
featuring a deep-ultraviolet cutoff edge. Theoretical investigations suggest that the ZrF8 …

Design of the Ionic Organic Nonlinear Optical Material NH4[LiC3H(CH3)O4] with Ultrawide Band Gap and Moderate Birefringence

H Tian, C Lin, Y Zhou, X Zhao, H Fan, T Yan… - Angewandte …, 2023 - Wiley Online Library
Ionic organic crystals containing organic planar π‐conjugated units has become one of the
hot spots as nonlinear optical (NLO) materials. However, although this type of ionic organic …

Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide

SP Guo, X Cheng, ZD Sun, Y Chi, BW Liu… - Angewandte …, 2019 - Wiley Online Library
A big challenge for nonlinear optical (NLO) materials is the application in high power lasers,
which needs the simultaneous occurrence of large second harmonic generation (SHG) and …

A3BBi(P2O7)2 (A = Rb, Cs; B = Pb, Ba): Isovalent Cation Substitution to Sustain Large Second-Harmonic Generation Responses

L Qi, Z Chen, X Shi, X Zhang, Q Jing, N Li… - Chemistry of …, 2020 - ACS Publications
Exploring novel photoelectric functional materials via chemical substitution-oriented design
is an effective strategy, which can be expanded to the discovery of high-performance UV …

Two pyrophosphates with large birefringences and second‐harmonic responses as ultraviolet nonlinear optical materials

X Lu, Z Chen, X Shi, Q Jing, MH Lee - Angewandte Chemie, 2020 - Wiley Online Library
Two new pyrophosphates nonlinear optical (NLO) materials, Rb3PbBi (P2O7) 2 (I) and
Cs3PbBi (P2O7) 2 (II), were successfully designed and synthesized. Both compounds …