Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals

C Benelli, D Gatteschi - Chemical Reviews, 2002 - ACS Publications
Rare-earth ions are characterized by large unquenched orbital angular momentum
associated with the internal nature of the valence f orbitals. In fact, with the exception of …

The structures and magnetic properties of complexes containing 3d-and 4f-metals

REP Winpenny - Chemical Society Reviews, 1998 - pubs.rsc.org
Heterometallic complexes containing 3d-/4f-metals have been made with a variety of ligands
including Schiff-bases, pyridonates and amino-alcohols. The majority of species with Schiff …

Systematic investigation of the nature of the coupling between a Ln (III) ion (Ln= Ce (III) to Dy (III)) and its aminoxyl radical ligands. structural and magnetic …

ML Kahn, JP Sutter, S Golhen… - Journal of the …, 2000 - ACS Publications
Numerous molecular compounds in which a paramagnetic Ln (III) ion is in interaction with a
second spin carrier such as a transition metal ion or an organic radical have been …

d–f Heteronuclear complexes: synthesis, structures and physicochemical aspects

M Sakamoto, K Manseki, H Ōkawa - Coordination Chemistry Reviews, 2001 - Elsevier
d–f Heteronuclear complexes: synthesis, structures and physicochemical aspects -
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Magnetic lanthanide–transition-metal organic–inorganic hybrid materials: From discrete clusters to extended frameworks

YG Huang, FL Jiang, MC Hong - Coordination Chemistry Reviews, 2009 - Elsevier
Magnetic lanthanide–transition-metal hybrid materials have enjoyed increasing attraction
because they not only provide examples for studying magnetic coupling involving …

A nonanuclear dysprosium (III)–copper (II) complex exhibiting single‐molecule magnet behavior with very slow zero‐field relaxation

C Aronica, G Pilet, G Chastanet… - Angewandte Chemie …, 2006 - Wiley Online Library
The discovery that some metal coordination clusters may behave as single-molecule
magnets (SMMs)[1–4] is currently stimulating abundant research in relation to potential …

Heterometallic CuII–LnIII complexes: Single molecule magnets and magnetic refrigerants

A Dey, P Bag, P Kalita, V Chandrasekhar - Coordination Chemistry …, 2021 - Elsevier
Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated
extensively for the past few years realizing the role of exchange interaction to minimize the …

Design and Magnetic Properties of a Magnetically Isolated GdIIICuII Pair. Crystal Structures of [Gd(hfa)3Cu(salen)], [Y(hfa)3Cu(salen)], [Gd(hfa)3Cu(salen)(Meim)], and [La(hfa)3(H2O)Cu …

I Ramade, O Kahn, Y Jeannin, F Robert - Inorganic Chemistry, 1997 - ACS Publications
The crystal structures of three compounds have been determined at room temperature,
namely [Gd (hfa) 3Cu (salen)](1),[Y (hfa) 3Cu (salen)](2), and [Gd (hfa) 3Cu …