Carbon-based nanostructures as a versatile platform for tunable π-magnetism

DG de Oteyza, T Frederiksen - Journal of Physics: Condensed …, 2022 - iopscience.iop.org
Emergence of π-magnetism in open-shell nanographenes has been theoretically predicted
decades ago but their experimental characterization was elusive due to the strong chemical …

Scanning probe microscopy in probing low-dimensional carbon-based nanostructures and nanomaterials

C Zhang, Z Yi, W Xu - Materials Futures, 2022 - iopscience.iop.org
Carbon, as an indispensable chemical element on Earth, has diverse covalent bonding
ability, which enables construction of extensive pivotal carbon-based structures in multiple …

Synthesis of a Porous [14] Annulene Graphene Nanoribbon and a Porous [30] Annulene Graphene Nanosheet on Metal Surfaces

T Qin, D Guo, J Xiong, X Li, L Hu… - Angewandte Chemie …, 2023 - Wiley Online Library
The electrical and mechanical properties of graphene‐based materials can be tuned by the
introduction of nanopores, which are sensitively related to the size, morphology, density, and …

Selective Activation of Aromatic C–H Bonds Catalyzed by Single Gold Atoms at Room Temperature

B Lowe, J Hellerstedt, A Matej, P Mutombo… - Journal of the …, 2022 - ACS Publications
Selective activation and controlled functionalization of C–H bonds in organic molecules is
one of the most desirable processes in synthetic chemistry. Despite progress in …

Tuning the diradical character of pentacene derivatives via non-benzenoid coupling motifs

T Wang, P Angulo-Portugal… - Journal of the …, 2023 - ACS Publications
The development of functional organic molecules requires structures of increasing size and
complexity, which are typically obtained by the covalent coupling of smaller building blocks …

Highly Selective On-Surface Ring-Opening of Aromatic Azulene Moiety

L Wang, X Peng, J Su, J Wang, A Gallardo… - Journal of the …, 2023 - ACS Publications
Controllable ring-opening of polycyclic aromatic hydrocarbons plays a crucial role in various
chemical and biological processes. However, breaking down aromatic covalent C–C bonds …

Steering On-Surface Reactions by Kinetic and Thermodynamic Strategies

T Wang, Q Fan, J Zhu - The Journal of Physical Chemistry Letters, 2023 - ACS Publications
On-surface synthesis has emerged as a powerful tool to fabricate various functional low-
dimensional nanostructures with atomic precision, thus becoming a promising platform for …

Recent progress in on-surface synthesis of nanoporous graphene materials

T Qin, T Wang, J Zhu - Communications Chemistry, 2024 - nature.com
Nanoporous graphene (NPG) materials are generated by removing internal degree-3
vertices from graphene and introducing nanopores with specific topological structures …

Controlled Hierarchical Dehydrogenation Reactions on Au (111)

H Zhu, Y Zheng, X Fan, J Wang, C Deng… - The Journal of …, 2023 - ACS Publications
X–H (X= N, C, O...) bonds are abundant among organic precursors; controllable scission of
hydrogenation atoms with high selectivity, therefore, has acquired extensive interest. In this …

Steering on-surface polymerization through coordination with a bidentate ligand

H Jiang, J Lu, F Zheng, Z Zhu, Y Yan… - Chemical …, 2023 - pubs.rsc.org
A double-chain structure was fabricated on Au (111) with a bromine-functionalized
phenanthroline precursor. We reveal the competition between the on-surface metal–ligand …