Light-induced spin crossover in Fe (II)-based complexes: The full photocycle unraveled by ultrafast optical and X-ray spectroscopies

A Cannizzo, CJ Milne, C Consani, W Gawelda… - Coordination Chemistry …, 2010 - Elsevier
The light-induced spin and structure changes upon excitation of the singlet metal-to-ligand
charge transfer (1MLCT) state of Fe (II)-polypyridine complexes are investigated in detail in …

Shedding new light on retinal protein photochemistry

A Wand, I Gdor, J Zhu, M Sheves… - Annual review of …, 2013 - annualreviews.org
The ultrafast spectroscopic investigation of novel retinal proteins challenges existing notions
concerning the course of primary events in these natural photoreceptors. We review two …

Vibrational Coherences and Relaxation in the High‐Spin State of Aqueous [FeII(bpy)3]2+

C Consani, M Prémont‐Schwarz… - Angewandte Chemie …, 2009 - Wiley Online Library
Iron (II)-based molecular complexes have been a subject of intense study since the
discovery of light-induced excitedstate spin trapping (LIESST).[1] In this process, excitation …

On the interplay between charge, spin and structural dynamics in transition metal complexes

M Chergui - Dalton Transactions, 2012 - pubs.rsc.org
This perspective presents some recent results concerning ultrafast intramolecular relaxation
processes in metal-based molecular complexes. Ultrafast electronic/vibrational relaxation at …

Coherent ultrafast torsional motion and isomerization of a biomimetic dipolar photoswitch

J Briand, O Bräm, J Réhault, J Léonard… - Physical Chemistry …, 2010 - pubs.rsc.org
Femtosecond fluorescence up-conversion, UV-Vis and IR transient absorption spectroscopy
are used to study the photo-isomerization dynamics of a new type of zwitterionic photoswitch …

Vibrational coherence transfer in the ultrafast intersystem crossing of a diplatinum complex in solution

R Monni, G Capano, G Auböck… - Proceedings of the …, 2018 - National Acad Sciences
We investigate the ultrafast transient absorption response of tetrakis (μ-pyrophosphito)
diplatinate (II),[Pt2 (μ-P2O5H2) 4] 4−[hereafter abbreviated Pt (pop)], in acetonitrile upon …

Vibronic Dynamics of the Ultrafast all-trans to 13-cis Photoisomerization of Retinal in Channelrhodopsin-1

C Schnedermann, V Muders, D Ehrenberg… - Journal of the …, 2016 - ACS Publications
Channelrhodopsins are light-gated ion channels with extensive applications in
optogenetics. Channelrhodopsin-1 from Chlamydomonas augustae (Ca ChR1) exhibits a …

Asymmetric toggling of a natural photoswitch: Ultrafast spectroscopy of Anabaena sensory rhodopsin

A Wand, R Rozin, T Eliash, KH Jung… - Journal of the …, 2011 - ACS Publications
Photochemistry in retinal proteins (RPs) is determined both by the properties of the retinal
chromophore and by its interactions with the surrounding protein. The initial retinal …

Conservation of vibrational coherence in ultrafast electronic relaxation: The case of diplatinum complexes in solution

R Monni, G Auböck, D Kinschel, KM Aziz-Lange… - Chemical Physics …, 2017 - Elsevier
We report the results of ultrafast transient absorption studies of tetrakis (μ-pyrophosphito)
diplatinate (II),[Pt 2 (μ-P 2 O 5 H 2) 4] 4−(Pt (pop)) and its perfluoroborated derivative [Pt 2 (μ …

Mechanistic origin of the vibrational coherence accompanying the photoreaction of biomimetic molecular switches

J Léonard, I Schapiro, J Briand, S Fusi… - … A European Journal, 2012 - Wiley Online Library
The coherent photoisomerization of a chromophore in condensed phase is a rare process in
which light energy is funneled into specific molecular vibrations during electronic relaxation …