From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Exploiting chemistry and molecular systems for quantum information science

MR Wasielewski, MDE Forbes, NL Frank… - Nature Reviews …, 2020 - nature.com
The power of chemistry to prepare new molecules and materials has driven the quest for
new approaches to solve problems having global societal impact, such as in renewable …

Persistent Radicals Derived from N-Heterocyclic Carbenes for Material Applications

H Song, E Pietrasiak, E Lee - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Persistent radicals are potential building blocks of novel materials in many
fields. Recently, highly stable persistent radicals are considered to be within reach, thanks to …

Recent advances in the chemistry of benzo [e][1, 2, 4] triazinyl radicals

FJM Rogers, PL Norcott, ML Coote - Organic & Biomolecular …, 2020 - pubs.rsc.org
Benzo [e][1, 2, 4] triazinyl, or Blatter radicals, are stable free radicals, first reported by Blatter
in 1968. In contrast to their nitroxide counterparts, their properties can be modified more …

Thermally and magnetically robust triplet ground state diradical

N Gallagher, H Zhang, T Junghoefer… - Journal of the …, 2019 - ACS Publications
High spin (S= 1) organic diradicals may offer enhanced properties with respect to several
emerging technologies, but typically exhibit low singlet triplet energy gaps and possess …

Synthesis and Thin Films of Thermally Robust Quartet (S = 3/2) Ground State Triradical

C Shu, M Pink, T Junghoefer, E Nadler… - Journal of the …, 2021 - ACS Publications
High-spin (S= 3/2) organic triradicals may offer enhanced properties with respect to several
emerging technologies, but those synthesized to date typically exhibit small doublet quartet …

Perspectives for polychlorinated trityl radicals

I Ratera, J Vidal-Gancedo, D Maspoch… - Journal of Materials …, 2021 - pubs.rsc.org
An organic free radical is a molecule with one or more unpaired electrons. Although most
free radicals are highly reactive, chemists have developed a few families of so-called …

Metal-free organic radical spin source

C Nicolaides, F Bazzi, E Vouros, DF Flesariu… - Nano Letters, 2023 - ACS Publications
Organic radicals have long been suggested as candidates for organic magnets and
components in organic spintronic devices. Herein, we demonstrate spin current emission …

[HTML][HTML] Blatter radical as a polymeric active material in organic batteries

A Saal, C Friebe, US Schubert - Journal of Power Sources, 2022 - Elsevier
The Blatter radical is applied in a cross-linked polymer to yield a stable and quickly
chargeable electrode material for organic radical batteries. Different electrolytes are …

Magnetic behavior in metal-free radical thin films

T Junghoefer, A Calzolari, I Baev, M Glaser, F Ciccullo… - Chem, 2022 - cell.com
Magnetism in organic materials is very intriguing: the realization of long-range magnetic
order in completely metal-free systems combines magnetic moments with useful properties …