Spin crossover in iron (III) complexes
Spin crossover compounds are a diverse class of switchable materials with applications
ranging from data storage devices to sensors. Iron (III) spin crossover complexes have …
ranging from data storage devices to sensors. Iron (III) spin crossover complexes have …
Solvent modified spin crossover in an iron (III) complex: phase changes and an exceptionally wide hysteresis
Solvent effects in a series of Fe (III) spin crossover (SCO) complexes [Fe (qsal-I) 2] OTf· sol
(sol= MeOH 1, EtOH 2, n-PrOH 3, i-PrOH 4, acetone 5 and MeCN 6) are explored. SCO is …
(sol= MeOH 1, EtOH 2, n-PrOH 3, i-PrOH 4, acetone 5 and MeCN 6) are explored. SCO is …
On the energetic stability of halogen bonds involving metals: implications in crystal engineering
I Benito, RM Gomila, A Frontera - CrystEngComm, 2022 - pubs.rsc.org
This work reports a combined computational and experimental analysis of the ability of
square planar d8 transition metal complexes to establish unconventional halogen bonding …
square planar d8 transition metal complexes to establish unconventional halogen bonding …
Bidirectional photoswitchability in an iron (III) spin crossover complex: symmetry-breaking and solvent effects
R Díaz-Torres, G Chastanet, E Collet, E Trzop… - Chemical …, 2023 - pubs.rsc.org
The impact of solvent on spin crossover (SCO) behaviour is reported in two solvates [Fe
(qsal-I) 2] NO3· 2ROH (qsal-I= 4-iodo-2-[(8-quinolylimino) methyl] phenolate; R= Me 1 or Et …
(qsal-I) 2] NO3· 2ROH (qsal-I= 4-iodo-2-[(8-quinolylimino) methyl] phenolate; R= Me 1 or Et …
Structural and theoretical insights into solvent effects in an iron (III) SCO complex
Alcohol effects in a series of iron (III) spin crossover complexes [Fe (qsal-Cl) 2] NO3· ROH
(R= Me 1, Et 2, 1-Pr 3) are explored. Despite the solvents differing from each other by only …
(R= Me 1, Et 2, 1-Pr 3) are explored. Despite the solvents differing from each other by only …
Spin Crossover in Iron(III) Quinolylsalicylaldiminates: The Curious Case of [Fe(qsal-F)2](Anion)
A family of iron (III) spin crossover complexes with different counteranions,[Fe (qsal-F) 2] A
(qsal-F= 4-fluoro-2-[(8-quinolylimino) methyl] phenolate; A= PF6–1, OTf–2, NO3–3, ClO4–4 …
(qsal-F= 4-fluoro-2-[(8-quinolylimino) methyl] phenolate; A= PF6–1, OTf–2, NO3–3, ClO4–4 …
Spin crossover in 3D metal centers binding halide-containing ligands: Magnetism, structure and computational studies
The capability of a given substance to change its spin state by the action of a stimulus, such
as a change in temperature, is by itself a very challenging property. Its interest is increased …
as a change in temperature, is by itself a very challenging property. Its interest is increased …
Intermolecular interaction tuning of spin-crossover iron (III) complexes with aromatic counteranions
Iron (III) spin-crossover (SCO) complexes [Fe (qsal) 2] BS· MeOH· H2O (1),[Fe (qsal) 2](NS)·
MeOH (2),[Fe (qnal) 2](NS)(3), and [Fe (qnal) 2] PS· MeOH· CH2Cl2 (4)(Hqsal, N-(8 …
MeOH (2),[Fe (qnal) 2](NS)(3), and [Fe (qnal) 2] PS· MeOH· CH2Cl2 (4)(Hqsal, N-(8 …
Evidence for surface effects on the intermolecular interactions in Fe (II) spin crossover coordination polymers
From X-ray absorption spectroscopy (XAS) and X-ray photoemission spectroscopy (XPS), it
is evident that the spin state transition behavior of Fe (II) spin crossover coordination …
is evident that the spin state transition behavior of Fe (II) spin crossover coordination …
Hysteretic spin crossover driven by anion conformational change
N Phukkaphan, DL Cruickshank, KS Murray… - Chemical …, 2017 - pubs.rsc.org
A new air stable FeIII spin crossover (SCO) complex has been synthesized. The compound
undergoes abrupt SCO near room temperature with T1/2 (↓)= 244 K and T1/2 (↑)= 278 K …
undergoes abrupt SCO near room temperature with T1/2 (↓)= 244 K and T1/2 (↑)= 278 K …