Realizing an efficient photochemical uranium reduction process using metal-free conjugated
polymers is highly desirable, but is extremely challenging, as it requires a broad photo …

The chemistry of actinide-nitrides has witnessed significant advances in the last ten years
with a large focus on uranium and a few breakthroughs with thorium. Following the early …

Cooperative chemistry between two or more metal centres can show enhanced reactivity
compared to the monometallic fragments. Given the paucity of actinide–metal bonds …

Ligands are known to play a crucial role in the construction of complexes with metal–metal
bonds. Compared with metal–metal bonds involving d-block transition metals, knowledge of …

Although examples of multiple bonds between actinide elements and main‐group elements
are quite common, studies of the multiple bonds between actinide elements and transition …

In the last few decades, photochemistry has great influence on all type of synthetic
processes. While photochemical synthesis is emerging field in inorganic chemistry as it …

The 2, 2′-bipyridyl-6, 6′-dicarboxylate ligand (bdc) has been shown in prior work to
effectively capture the uranyl (VI) ion, UO22+, from aqueous solutions. However, the redox …

Reaction of the potassium pentamethylcyclopentadienyl iridate tris-hydride K [IrCp* H3] with
UCl4 and ThCl4 (DME) 2 led to the complete replacement of the halide ligands to generate …

The monomeric and dimeric uranium azide complexes {[(CH3) 2NCH2CH2NPiPr2] 2U (N3)
2}(2) and {[(CH3) 2NCH2CH2NPiPr2] 2U (N3) 2} 2 (3) were synthesized by treating complex …

A double-layer N–P ligand-supported uranium azide complex 2 ([N (CH2CH2NP i Pr2)
3UN3] 2) was synthesized by the reaction of a uranium precursor [N (CH2CH2NP i Pr2) …