Electron and ion transport in lithium and lithium-ion battery negative and positive composite electrodes

CD Quilty, D Wu, W Li, DC Bock, L Wang… - Chemical …, 2023 - ACS Publications
Electrochemical energy storage systems, specifically lithium and lithium-ion batteries, are
ubiquitous in contemporary society with the widespread deployment of portable electronic …

Size dependent behavior of Fe 3 O 4 crystals during electrochemical (de) lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission …

DC Bock, CJ Pelliccione, W Zhang… - Physical Chemistry …, 2017 - pubs.rsc.org
The iron oxide magnetite, Fe3O4, is a promising conversion type lithium ion battery anode
material due to its high natural abundance, low cost and high theoretical capacity. While the …

Equilibria and rate phenomena from atomistic to mesoscale: simulation studies of magnetite

CN Lininger, NW Brady, AC West - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Batteries are dynamic devices composed of multiple components that operate
far from equilibrium and may operate under extreme stress and varying loads. Studies of …

Energetics of lithium insertion into magnetite, defective magnetite, and maghemite

CN Lininger, CA Cama, KJ Takeuchi… - Chemistry of …, 2018 - ACS Publications
At low concentrations of lithium insertion into inverse spinel magnetite Fe3O4, a phase
change to rock-salt-like Li x Fe3O4 has been observed. We used density-functional-theory …

Carbon nanofibers impregnated with Fe3O4 nanoparticles as a flexible and high capacity negative electrode for lithium-ion batteries

CA Velásquez, FA Vásquez, M Alvarez-Láinez… - Journal of Alloys and …, 2021 - Elsevier
The development of E-textiles requires portable devices for energy storage that do not
compromise the comfort and functionality of the textile. In this work, a flexible carbon …

Isothermal Microcalorimetry: Insight into the Impact of Crystallite Size and Agglomeration on the Lithiation of Magnetite, Fe3O4

MM Huie, DC Bock, AM Bruck, KR Tallman… - … applied materials & …, 2019 - ACS Publications
Magnetite, Fe3O4, holds significant interest as a Li-ion anode material because of its high
theoretical capacity (926 mAh/g) associated with multiple electron transfers per cation …

Multi-electron transfer enabled by topotactic reaction in magnetite

W Zhang, Y Li, L Wu, Y Duan, K Kisslinger… - Nature …, 2019 - nature.com
A bottleneck for the large-scale application of today's batteries is low lithium storage
capacity, largely due to the use of intercalation-type electrodes that allow one or less …

The systematic refinement for the phase change and conversion reactions arising from the lithiation of magnetite nanocrystals

CN Lininger, AM Bruck, DM Lutz… - Advanced Functional …, 2020 - Wiley Online Library
Nanostructured materials can exhibit phase change behavior that deviates from the
macroscopic phase behavior. This is exemplified by the ambiguity for the equilibrium phases …

Temporally and Spatially Resolved Visualization of Electrochemical Conversion: Monitoring Phase Distribution During Lithiation of Magnetite (Fe3O4) Electrodes

AM Bruck, NW Brady, CN Lininger… - ACS Applied Energy …, 2019 - ACS Publications
Fundamental understanding of transport properties across multiple size regimes is critical for
the rational design of electrodes with conversion materials. While recent studies have …

[图书][B] The mechanistic description of the open circuit potential for the lithiation of magnetite nanoparticles

CN Lininger - 2018 - search.proquest.com
Batteries are ubiquitous in modern society, from the portable devices we use daily to the yet-
to-be realized integration of batteries into the electrical grid and electrical vehicle markets …