Sodium Periodate (NaIO4) in Organic Synthesis
NaIO4 has been effectively investigated as a flexible oxidant for a range of fundamental
chemical transformations, including the synthesis of bioactive natural compounds and …
chemical transformations, including the synthesis of bioactive natural compounds and …
[HTML][HTML] Ruthenium tetroxide oxidation of N-methyl-isoxazolidine: Computational mechanistic study
MA Chiacchio, D Iannazzo, SV Giofrè, R Romeo… - Arabian Journal of …, 2022 - Elsevier
In this paper, we report a mechanistic study of RuO 4-catalyzed oxidation on the 2-
methylisoxazolidine through computational methods. The investigation was performed taken …
methylisoxazolidine through computational methods. The investigation was performed taken …
N–H insertion reaction via an iron carbenoid from α-diazophenylpropionate and its application to the formal total synthesis of stizolobinic acid
H Shinohara, H Saito, H Homma, K Mizuta, S Miyairi… - Tetrahedron, 2020 - Elsevier
The formal total synthesis of the non-proteinogenic amino acid stizolobinic acid was
accomplished relying as key step on an iron carbenoid-based N–H insertion reaction. The N …
accomplished relying as key step on an iron carbenoid-based N–H insertion reaction. The N …
[PDF][PDF] Sodium Periodate (NaIO4) in Organic Synthesis
N Dubasib, V Seemac, V Kotrad - 2023 - academia.edu
Sodium Periodate (NaIO4) in Organic Synthesis Page 1 548 © 2023. The Author(s). SynOpen
2023, 7, 548–554 Georg Thieme Verlag KG, Rüdigerstraße 14, 70469 Stuttgart, Germany R …
2023, 7, 548–554 Georg Thieme Verlag KG, Rüdigerstraße 14, 70469 Stuttgart, Germany R …
[PDF][PDF] RuO4-MEDIATED OXIDATION OF TERTIARY AMINES. STEREOELECTRONIC EFFECTS
H Petride, C Florea, A Hirtopeanu… - Rev. Roum …, 2020 - researchgate.net
Tertiary amines like PhCH2-NMe-CH2R (R= H, Me, CN) underwent RuO4-mediated
oxidation by attack at all three N-α-positions. The various reaction products were classified …
oxidation by attack at all three N-α-positions. The various reaction products were classified …
[PDF][PDF] HOMOLYTIC PATHWAY FOR THE RuO4-OXIDATION OF AMINES
CA Florea, H Petride - Rev. Roum. Chim, 2019 - researchgate.net
It is well known that secondary amines carrying CH bonds in α to N atom (R-NH-CHR2)
undergo oxidation by ruthenium-based catalysts1, 2 (including ruthenium tetroxide) 3-5 to …
undergo oxidation by ruthenium-based catalysts1, 2 (including ruthenium tetroxide) 3-5 to …
[PDF][PDF] RuO4-mediated oxidation of N-benzylated tertiary amines. Four-and three-membered azacycloalkanes as substrates
CA Florea, A Hîrtopeanu, C Stavarache… - Organic …, 2018 - researchgate.net
Similarly to N-benzylpiperidine and-pyrrolidine, N-benzylazetidine underwent RuO4-
catalyzed oxidation by attack at both types of N-methylene CH bonds: endocyclic and …
catalyzed oxidation by attack at both types of N-methylene CH bonds: endocyclic and …
[PDF][PDF] 金属カルベン錯体を基軸とするNH 挿入反応の開発とアミノ酸誘導体合成への展開
篠原秀幸 - 2021 - nihon-u.repo.nii.ac.jp
医薬品の開発において窒素原子を有する生物活性分子のデザインと合成は重要な分野であり, 炭素
(C)-窒素 (N) 結合を構築する新規反応の開発は大きな課題の一つである. 本論文は …
(C)-窒素 (N) 結合を構築する新規反応の開発は大きな課題の一つである. 本論文は …