Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design

Y Zhao, DP Adiyeri Saseendran, C Huang… - Chemical …, 2023 - ACS Publications
The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are core steps of
various energy conversion and storage systems. However, their sluggish reaction kinetics …

Water electrolysis

AJ Shih, MCO Monteiro, F Dattila, D Pavesi… - Nature Reviews …, 2022 - nature.com
Electrochemistry has the potential to sustainably transform molecules with electrons
supplied by renewable electricity. It is one of many solutions towards a more circular …

Hydrogen spillover-bridged Volmer/Tafel processes enabling ampere-level current density alkaline hydrogen evolution reaction under low overpotential

HQ Fu, M Zhou, PF Liu, P Liu, H Yin… - Journal of the …, 2022 - ACS Publications
Water-alkaline electrolysis holds a great promise for industry-scale hydrogen production but
is hindered by the lack of enabling hydrogen evolution reaction electrocatalysts to operate at …

Modifying redox properties and local bonding of Co3O4 by CeO2 enhances oxygen evolution catalysis in acid

J Huang, H Sheng, RD Ross, J Han, X Wang… - Nature …, 2021 - nature.com
Developing efficient and stable earth-abundant electrocatalysts for acidic oxygen evolution
reaction is the bottleneck for water splitting using proton exchange membrane electrolyzers …

Double-atom catalysts as a molecular platform for heterogeneous oxygen evolution electrocatalysis

L Bai, CS Hsu, DTL Alexander, HM Chen, X Hu - Nature Energy, 2021 - nature.com
The oxygen evolution reaction (OER) is an essential anode reaction for the generation of
fuels through water splitting or CO2 electroreduction. Mixed metal oxides containing Co, Fe …

Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites

H Yang, F Li, S Zhan, Y Liu, W Li, Q Meng… - Nature Catalysis, 2022 - nature.com
Exploration of efficient water oxidation catalysts (WOCs) is the primary challenge in
conversion of renewable energy into fuels. Here we report a molecularly well-defined …

S‐Doping triggers redox reactivities of both iron and lattice oxygen in FeOOH for low‐cost and high‐performance water oxidation

X Chen, Q Wang, Y Cheng, H Xing, J Li… - Advanced Functional …, 2022 - Wiley Online Library
Developing low‐cost and highly efficient earth‐abundant oxygen evolution reaction (OER)
electrocatalysts via an energy‐and time‐saving method is of great significance to the …

Unraveling Sequential Oxidation Kinetics and Determining Roles of Multi-Cobalt Active Sites on Co3O4 Catalyst for Water Oxidation

W Kang, R Wei, H Yin, D Li, Z Chen… - Journal of the …, 2023 - ACS Publications
The multi-redox mechanism involving multi-sites has great implications to dictate the
catalytic water oxidation. Understanding the sequential dynamics of multi-steps in oxygen …

Mechanism of oxygen evolution catalyzed by cobalt oxyhydroxide: cobalt superoxide species as a key intermediate and dioxygen release as a rate-determining step

A Moysiadou, S Lee, CS Hsu, HM Chen… - Journal of the American …, 2020 - ACS Publications
The oxygen evolution reaction (OER) is the performance-limiting half reaction of water
splitting, which can be used to produce hydrogen fuel using renewable energies. Whereas a …

Understanding the Roles of Electrogenerated Co3+ and Co4+ in Selectivity‐Tuned 5‐Hydroxymethylfurfural Oxidation

X Deng, GY Xu, YJ Zhang, L Wang, J Zhang… - Angewandte …, 2021 - Wiley Online Library
The Co‐based electrocatalyst is among the most promising candidates for electrochemical
oxidation of 5‐hydroxymethylfurfural (HMF). However, the intrinsic active sites and detailed …