The carbon–carbon (C–C) bond cleavage of cyclopropanols is a wide area of research with
much current activity. This review highlights new developments in this area over the past two …

In recent years, radical C–C bond cleavage reactions have been increasingly understood
and used to perform transformations that complement traditional ionic processes. However …

Carbon–carbon/carbon–heteroatom bond formation via oxidative transformations is a
heavily explored topic at the frontier of chemistry. Potassium persulfate (K2S2O8) has …

Silver, known and utilized since ancient times, is a coinage metal, which has been widely
used for various organic transformations in the past few decades. Currently, the silver …

Under oxidative conditions, 1, 4-dihydropyridines (DHPs) undergo a homolytic cleavage,
forming exclusively a Csp3-centered radical that can engage in the C–H alkylation of …

A novel, manganese‐catalyzed oxidative azidation of cyclobutanols is described. A wide
range of primary, secondary, and tertiary alkyl azides were generated in synthetically useful …

Abstract A novel C− C bond‐forming strategy employing manganese‐catalyzed ring‐
opening of cyclobutanol substrates, followed by cyanation or ethynylation, is described. A …

Established herein is a radical-mediated C–H alkylation of enamides with cyclopropanols.
An environmentally benign catalytic system with iron salt and air is used to permit the …

Due to their high strain, unique bonding and relative ease of ring-cleavage, and because
they are readily accessible, cyclopropanols have been employed in an increasing number of …

The C–C bond located at the β-position of an alkoxy radical readily breaks to form an alkyl
radical along with a carbonyl compound. Such processes are called β-scission or β …