Trifluoromethoxylation reactions of (hetero) arenes, olefinic systems and aliphatic saturated substrates

S Barata‐Vallejo, SM Bonesi… - Chemistry–A European …, 2022 - Wiley Online Library
Direct fluoroalkoxylation reactions of (hetero) arenes, carbon‐carbon multiple bonds, and
substitution reactions at Csp3 carbon centers by CF3O, CHF2O, and (CF3) 2CFO groups are …

Nanocellulose as Convenient Reaction Media for the FeCl3 Mediated Mechanochemical Synthesis of 3-Acylchromones

S Mkrtchyan, VB Purohit… - … Sustainable Chemistry & …, 2023 - ACS Publications
A solvent free strategy for the mechanochemical synthesis of 3-acylchromones has been
developed via FeCl3-nanocellulose mediated dehydrative coupling of ortho …

Mechanochemical Defluorinative Acylation of ortho‐Hydroxyarylenaminones by CF3‐Compounds: Synthesis of 3‐Acylchromones

S Mkrtchyan, VB Purohit, S Khutsishvili… - Advanced Synthesis …, 2023 - Wiley Online Library
An alternative strategy for the mechanochemical defluorinative acylation of ortho‐
hydroxyarylenaminones has been developed to synthesise 3‐acylchromones utilizing CF3 …

Nanocellulose as a Reaction Media and Stoichiometric Reagent for FeCl3-Mediated Reductive Functionalization of Nitro Compounds

S Mkrtchyan, VB Purohit, J Zapletal… - ACS Sustainable …, 2023 - ACS Publications
Among a wide array of synthetic amides, N-aryl/alkyl amides are an important class of
structural motifs having significant importance in pharmaceutical and agrochemical …

Skeletal rearrangement through photocatalytic denitrogenation: access to C-3 aminoquinolin-2 (1 H)-ones

S Singh, G Chakrabortty, SR Roy - Chemical Science, 2023 - pubs.rsc.org
The addition of an amine group to a heteroaromatic system is a challenging synthetic
process, yet it is an essential one in the development of many bioactive molecules. Here, we …

Bio‐Inspired Deaminative Hydroxylation of Aminoheterocycles and Electron‐Deficient Anilines

C Ghiazza, L Wagner, S Fernández… - Angewandte Chemie …, 2023 - Wiley Online Library
Among the tools available to chemists for drug design of bioactive compounds, the
bioisosteric replacement of atoms or groups of atoms is the cornerstone of modern …

Development and application of trifluoromethoxylating reagents

Y Si, P Tang - Chinese Journal of Chemistry, 2023 - Wiley Online Library
Comprehensive Summary The trifluoromethoxy functional group has received increasing
attention in recent years due to its distinctive properties such as good metabolic stability …

Mechanochemical arylative detrifluoromethylation of trifluoromethylarenes

S Mkrtchyan, M Shkoor, S Sarfaraz, K Ayub… - Organic & …, 2023 - pubs.rsc.org
The stoichiometric defluorinative functionalization of ArCF3 is a conceptually appealing
research target. It enables the challenging late-stage functionalization of CF3-containing …

Metal-free, tert-butyl nitrite promoted C (sp 2)–S coupling reaction: the synthesis of aryl dithiocarbamates and analysis of antimicrobial activity by 'in silico'and 'in vitro' …

S Pal, S Sarkar, A Mukherjee, A Kundu, A Sen… - Green …, 2023 - pubs.rsc.org
An environmentally friendly, metal-free, and efficient C (sp2)–S coupling reaction protocol
between aniline and low-cost tetraalkylthiuram disulfides was developed to synthesize aryl …

Unexpected side reactions dominate the oxidative transformation of aromatic amines in the Co (II)/peracetic acid system

JH Wu, TH Yang, F Chen, HQ Yu - PNAS nexus, 2024 - academic.oup.com
Aromatic amines (AAs), ubiquitous in industrial applications, pose significant environmental
hazards due to their resistance to conventional wastewater treatments. Peracetic acid (PAA) …