Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization

C Jérôme, P Lecomte - Advanced drug delivery reviews, 2008 - Elsevier
Advanced drug delivery systems rely on the availability of biocompatible materials.
Moreover, biodegradability is highly desirable in the design of those systems. Consequently …

Biotechnological routes based on lactic acid production from biomass

C Gao, C Ma, P Xu - Biotechnology advances, 2011 - Elsevier
Lactic acid, the most important hydroxycarboxylic acid, is now commercially produced by the
fermentation of sugars present in biomass. In addition to its use in the synthesis of …

Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates

N Ajellal, JF Carpentier, C Guillaume… - Dalton …, 2010 - pubs.rsc.org
This Perspective article summarizes efforts paid in our group to develop efficient metal-
based catalysts for the immortal ring-opening polymerization (iROP) of cyclic esters in the …

Synthesis, structure and properties of poly (L-lactide-co-ε-caprolactone) statistical copolymers

J Fernández, A Etxeberria, JR Sarasua - Journal of the Mechanical …, 2012 - Elsevier
Four poly (L-lactide-co-ε-caprolactone)(PLCL) copolymers were synthesized at 120, 130,
140 and 150° C by ring opening polymerization using stannous octoate catalyst at a 2000: 1 …

A Multitool for Circular Economy: Fast Ring‐Opening Polymerization and Chemical Recycling of (Bio) polyesters Using a Single Aliphatic Guanidine Carboxy Zinc …

M Fuchs, PM Schäfer, W Wagner, I Krumm… - …, 2023 - Wiley Online Library
A new aliphatic hybrid guanidine N, O‐donor ligand (TMGeech) and its zinc chloride
complex ([ZnCl2 (TMGeech)]) are presented. This complex displays high catalytic activity for …

Recent developments in enzyme-catalyzed ring-opening polymerization

AC Albertsson, RK Srivastava - Advanced drug delivery reviews, 2008 - Elsevier
An exponential growth has been observed in the last decade where enzymes were used as
catalysts for polymerization of different monomers and due to enzyme's origin from natural …

Recent developments in ring-opening polymerization of lactones

P Lecomte, C Jérôme - Synthetic biodegradable polymers, 2012 - Springer
Polylactones are important biodegradable and biocompatible environmentally friendly
polyesters widely used for many applications and more particularly for biomedical …

Zinc Aryl/Alkyl β-diketiminates: Balancing Accessibility and Stability for High-Activity Ring-Opening Polymerization of rac-Lactide

JE Chellali, AK Alverson, JR Robinson - ACS Catalysis, 2022 - ACS Publications
The development of nontoxic initiators which display both high activity and stability at low
catalyst concentrations can be challenging, as these desired attributes often involve …

Catalytic ring-opening copolymerization of limonene oxide and phthalic anhydride: Toward partially renewable polyesters

EH Nejad, A Paoniasari, CGW van Melis… - …, 2013 - ACS Publications
Catalytic ring-opening copolymerization of limonene oxide with phthalic anhydride was
performed applying metal t-Bu–salophen complexes (t-Bu–salophen) MX; M= Cr, X= Cl (1) …

A Strategy for Control of “Random” Copolymerization of Lactide and Glycolide: Application to Synthesis of PEG-b-PLGA Block Polymers Having Narrow Dispersity

H Qian, AR Wohl, JT Crow, CW Macosko… - Macromolecules, 2011 - ACS Publications
Poly (lactic-co-glycolic acid)(PLGA) is a biodegradable copolymer that is also acceptable for
use in a variety of biomedical applications. Typically, a random PLGA polymer is …