Quest for ion–ion correlations in electric double layers and overcharging phenomena

J Lyklema - Advances in colloid and interface science, 2009 - Elsevier
A discussion is given of the experimental evidence for overcharging, also known as charge
reversal. The phenomenon is very common. The most general explanation is specific …

Simple hofmeister series

J Lyklema - Chemical Physics Letters, 2009 - Elsevier
Hofmeister, or lyotropic, series date back to 1888, when the founder arranged a large
number of electrolytes in sequences with respect to their effectiveness salting out egg white …

Effective charge saturation in colloidal suspensions

L Bocquet, E Trizac, M Aubouy - The Journal of Chemical Physics, 2002 - pubs.aip.org
Because micro-ions accumulate around highly charged colloidal particles in electrolyte
solutions, the relevant parameter to compute their interactions is not the bare charge, but an …

Alexander's prescription for colloidal charge renormalization

E Trizac, L Bocquet, M Aubouy, HH von Grünberg - Langmuir, 2003 - ACS Publications
The interactions between charged colloidal particles in an electrolyte may be described by
usual Debye− Hückel theory provided the source of the electric field is suitably …

Permeation across hydrated DPPC lipid bilayers: simulation of the titrable amphiphilic drug valproic acid

J Ulander, ADJ Haymet - Biophysical journal, 2003 - cell.com
Valproic acid is a short branched fatty acid used as an anticonvulsant drug whose
therapeutic action has been proposed to arise from membrane-disordering properties. Static …

Hybrid boundary element and finite difference method for solving the nonlinear Poisson–Boltzmann equation

AH Boschitsch, MO Fenley - Journal of computational chemistry, 2004 - Wiley Online Library
A hybrid approach for solving the nonlinear Poisson–Boltzmann equation (PBE) is
presented. Under this approach, the electrostatic potential is separated into (1) a linear …

Sensing the structural and conformational properties of single-stranded nucleic acids using electrometry and molecular simulations

R Walker-Gibbons, X Zhu, A Behjatian, TJD Bennett… - Scientific Reports, 2024 - nature.com
Inferring the 3D structure and conformation of disordered biomolecules, eg, single stranded
nucleic acids (ssNAs), remains challenging due to their conformational heterogeneity in …

Decay behavior of screened electrostatic surface forces in ionic liquids: the vital role of non-local electrostatics

R Kjellander - Physical Chemistry Chemical Physics, 2016 - pubs.rsc.org
Screened electrostatic surface forces, also called double layer forces, between surfaces in
ionic liquids can, depending on the circumstances, decay in an exponentially damped …

Far-field electrostatic signatures of macromolecular 3D conformation

G Kloes, TJD Bennett, A Chapet-Batlle, A Behjatian… - Nano …, 2022 - ACS Publications
In solution as in vacuum, the electrostatic field distribution in the vicinity of a charged object
carries information on its three-dimensional geometry. We report on an experimental study …

A systematic way to extend the Debye–Huckel theory beyond dilute electrolyte solutions

T Xiao, X Song - The Journal of Physical Chemistry A, 2021 - ACS Publications
An extended Debye–Hückel theory with fourth order gradient term is developed for
electrolyte solutions; namely, the electric potential φ (r) of the bulk electrolyte solution can be …