Emerging Trends in Cross-Coupling: Twelve-Electron-Based L1Pd(0) Catalysts, Their Mechanism of Action, and Selected Applications

SJ Firsan, V Sivakumar, TJ Colacot - Chemical Reviews, 2022 - ACS Publications
Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Bimetallic catalysis in stereodivergent synthesis

X Huo, G Li, X Wang, W Zhang - Angewandte Chemie, 2022 - Wiley Online Library
Bimetallic catalysis has emerged as an efficient strategy for the development of new
chemical reactions. Importantly, this strategy also provides a simple and powerful platform …

Synergistic dual transition metal catalysis

UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

Enantio-and diastereodivergent construction of 1, 3-nonadjacent stereocenters bearing axial and central chirality through synergistic Pd/Cu catalysis

J Zhang, X Huo, J Xiao, L Zhao, S Ma… - Journal of the American …, 2021 - ACS Publications
In contrast to the widely explored methods for the asymmetric synthesis of molecules
bearing a single stereocenter or adjacent stereocenters, the concurrent construction of 1, 3 …

Asymmetric synthesis of allylic compounds via hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes

G Li, X Huo, X Jiang, W Zhang - Chemical Society Reviews, 2020 - pubs.rsc.org
Hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes are widely
utilized in the synthesis of valuable allylic compounds. In the past decades, asymmetric …

Bimetallic cooperation across the periodic table

J Campos - Nature Reviews Chemistry, 2020 - nature.com
Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …

Merging photoinduced iron-catalyzed decarboxylation with copper catalysis for C–N and C–C couplings

N Xiong, Y Li, R Zeng - ACS Catalysis, 2023 - ACS Publications
We report a photoinduced iron/copper dual-catalytic strategy for the radical decarboxylation
functionalization of aliphatic carboxylic acids. The photoinduced ligand-to-iron charge …

Stereodivergent Synthesis of Allenes with α, β‐Adjacent Central Chiralities Empowered by Synergistic Pd/Cu Catalysis

L Zhao, Y Luo, J Xiao, X Huo, S Ma… - Angewandte Chemie …, 2023 - Wiley Online Library
The stereodivergent synthesis of allene compounds bearing α, β‐adjacent central chiralities
has been realized via the Pd/Cu‐catalyzed dynamic kinetic asymmetric alkylation of racemic …

Noncovalent interactions in metal complex catalysis

KT Mahmudov, AV Gurbanov, FI Guseinov… - Coordination Chemistry …, 2019 - Elsevier
Metal complex catalysis, in which coordination compounds are designed as catalysts for
chemical transformations employing noncovalent interactions, is emerging as a powerful …

Multimetallic-catalyzed C–C bond-forming reactions: from serendipity to strategy

LKG Ackerman-Biegasiewicz… - Journal of the …, 2023 - ACS Publications
The use of two or more metal catalysts in a reaction is a powerful synthetic strategy to access
complex targets efficiently and selectively from simple starting materials. While capable of …