Mirror symmetry breaking in liquids and liquid crystals

C Tschierske - Liquid Crystals, 2018 - Taylor & Francis
In the recent two decades liquid crystal science has contributed significantly to the
understanding of mirror symmetry breaking and spontaneous emergence of chirality in …

Chemical and physical aspects of recent bent-shaped liquid crystals exhibiting chiral and achiral mesophases

S Kaur, V Punjani, N Yadav, A Barthakur, A Baghla… - Liquid …, 2022 - Taylor & Francis
Bent-core liquid crystals (BLCs) are a class of thermotropic LCs that exhibit chiral and polar
superstructures in achiral molecules. Progress in design and synthesis of novel bent-core …

Cybotactic nematic liquid crystal–an overview

AK Nasir, M Rahman - Liquid Crystals, 2024 - Taylor & Francis
The recent identification of ferroelectricity within the nematic phase of liquid crystals has
triggered significant interest. However, prior to this discovery; the potential existence of …

On the structure of the Nx phase of symmetric dimers: inferences from NMR

A Hoffmann, AG Vanakaras, A Kohlmeier, GH Mehl… - Soft Matter, 2015 - pubs.rsc.org
NMR measurements on a selectively deuterated liquid crystal dimer CB-C9-CB, exhibiting
two nematic phases, show that the molecules in the lower temperature nematic phase, NX …

A comparison of the conformational distributions of the achiral symmetric liquid crystal dimer CB7CB in the achiral nematic and chiral twist-bend nematic phases

JW Emsley, M Lelli, A Lesage… - The Journal of Physical …, 2013 - ACS Publications
The sets of residual dipolar couplings between carbon and hydrogen nuclei obtained from
the proton-encoded 13C 2D NMR experiment are used to investigate the conformational …

Entropy stabilized form chirality in curved rod nematics: structure and symmetries.

AG Vanakaras, E Samulski, DJ Photinos - Soft Matter, 2025 - pubs.rsc.org
Monte Carlo molecular simulations of curve-shaped rods show the propensity of such
shapes to polymorphism revealing both smectic and polar nematic phases. The nematic …

Towards understanding the N TB phase: a combined experimental, computational and spectroscopic study

T Ivšić, M Vinković, U Baumeister, A Mikleušević… - RSC …, 2016 - pubs.rsc.org
Today liquid-crystalline materials are most widely exploited for flat-panel displays, and yet
their ability to self-organize into periodically ordered nanostructures gives rise to a broad …

[HTML][HTML] In silico study of liquid crystalline phases formed by bent-shaped molecules with excluded volume type interactions

P Kubala, W Tomczyk, M Cieśla - Journal of Molecular Liquids, 2022 - Elsevier
What impact does the mesogens' shape have on the formation of the liquid crystalline
phase? Using Monte Carlo and molecular dynamics simulations we numerically studied a …

Evidence of biaxial order in the cybotactic nematic phase of bent-core mesogens

F Vita, T Tauscher, F Speetjens, ET Samulski… - Chemistry of …, 2014 - ACS Publications
Thermotropic biaxial nematics melts exhibiting three distinct directions of molecular
orientational order 1 have attracted considerable interest as promising candidates for a …

Stereochemical Rules Govern the Soft Self‐Assembly of Achiral Compounds: Understanding the Heliconical Liquid‐Crystalline Phases of Bent‐Core Mesogens

A Lehmann, M Alaasar, M Poppe… - … A European Journal, 2020 - Wiley Online Library
A series of bent‐shaped 4‐cyanoresorcinol bisterephthalates is reported. Some of these
achiral compounds spontaneously form a short‐pitch heliconical lamellar liquid‐crystalline …