The Current Understanding of Mechanistic Pathways in Zeolite Crystallization

AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …

Illuminating the Black Box: A Perspective on Zeolite Crystallization in Inorganic Media

K Asselman, C Kirschhock… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Since the discovery of synthetic zeolites in the 1940s and their implementation
in major industrial processes involving adsorption, catalytic conversion, and ion exchange …

[HTML][HTML] Green synthesis and characterization of zinc oxide nanoparticles using Eucalyptus globulus Labill. leaf extract and zinc nitrate hexahydrate salt

AA Barzinjy, HH Azeez - SN Applied Sciences, 2020 - Springer
This study consists of a reliable process for synthesizing ZnO NPs by green method. Here,
Eucalyptus globulus Labill. leaf extract is utilized as an efficient chelating and capping agent …

In situ imaging of silicalite-1 surface growth reveals the mechanism of crystallization

AI Lupulescu, JD Rimer - Science, 2014 - science.org
The growth mechanism of silicalite-1 (MFI zeolite) is juxtaposed between classical models
that postulate silica molecules as primary growth units and nonclassical pathways based on …

Structure-directing behaviors of tetraethylammonium cations toward zeolite beta revealed by the evolution of aluminosilicate species formed during the crystallization …

T Ikuno, W Chaikittisilp, Z Liu, T Iida… - Journal of the …, 2015 - ACS Publications
Organic structure-directing agents (OSDAs) have been widely used for the synthesis of
zeolites. In most cases, OSDAs are occluded in zeolites as an isolated cation or molecule …

[PDF][PDF] Kinetic Control of Metal–Organic Framework Crystallization Investigated by Time‐Resolved In Situ X‐Ray Scattering

E Stavitski, M Goesten, J Juan‐Alcañiz… - Angewandte Chemie, 2011 - uu.nl
Metal–organic frameworks (MOFs) are among the most sophisticated nanostructured solids:
they often possess high surface areas and pore volumes, with the possibility of finetuning …

[HTML][HTML] Effect of interparticle interactions on size determination of zirconia and silica based systems–A comparison of SAXS, DLS, BET, XRD and TEM

S Pabisch, B Feichtenschlager, G Kickelbick… - Chemical physics …, 2012 - Elsevier
The aim of this work is a systematic comparison of size characterisation methods for two
completely different model systems of oxide nanoparticles, ie amorphous spherical silica …

Hierarchical mesoporous zeolites: Direct self‐assembly synthesis in a conventional surfactant solution by kinetic control over the zeolite seed formation

Y Zhu, Z Hua, J Zhou, L Wang, J Zhao… - … A European Journal, 2011 - Wiley Online Library
By kinetic control over the zeolite seed formation, we report the direct fabrication of
hierarchical mesoporous zeolites using hexadecyl trimethyl ammonium bromide (CTAB) as …

[HTML][HTML] Transient modes of zeolite surface growth from 3D gel-like islands to 2D single layers

M Kumar, MK Choudhary, JD Rimer - Nature communications, 2018 - nature.com
Zeolite crystallization occurs by multifaceted processes involving molecule attachment and
nonclassical pathways governed by the addition of amorphous precursors. Here, we use …

UV Raman spectroscopic study on the synthesis mechanism and assembly of molecular sieves

F Fan, Z Feng, C Li - Chemical Society Reviews, 2010 - pubs.rsc.org
In the past decade, UV Raman spectroscopy has become a powerful technique for the
characterization of the synthesis mechanism and assembly of molecular sieves. Ultraviolet …