Recent advances in the assembly of high-nuclearity lanthanide clusters
XY Zheng, J Xie, XJ Kong, LS Long… - Coordination Chemistry …, 2019 - Elsevier
High-nuclearity lanthanide clusters have attracted much attention in different fields because
of their unique physical and chemical properties and their potential applications. In this …
of their unique physical and chemical properties and their potential applications. In this …
Polyoxometalate-assisted synthesis of transition-metal cubane clusters as artificial mimics of the oxygen-evolving center of photosystem II
ZJ Liu, XL Wang, C Qin, ZM Zhang, YG Li… - Coordination chemistry …, 2016 - Elsevier
Abstract The {Mn 4 O 5 Ca} cluster of photosystem II is a well-known cubane-like transition-
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …
Four‐Shell Polyoxometalates Featuring High‐Nuclearity Ln26 Clusters: Structural Transformations of Nanoclusters into Frameworks Triggered by Transition‐Metal …
Z Li, XX Li, T Yang, ZW Cai, ST Zheng - Angewandte Chemie, 2017 - Wiley Online Library
A series of polyoxometalates (POMs) that incorporate the highest‐nuclearity Ln clusters that
have been observed in such structures to date (Ln26, Ln= La and Ce) are described, which …
have been observed in such structures to date (Ln26, Ln= La and Ce) are described, which …
Poly (polyoxotungstate) s with 20 nickel centers: from nanoclusters to one‐dimensional chains
The design and synthesis of transition-metal (TM) substituted polyoxotungstates (POTs) is of
contemporary interest, owing to their putative and realized applications in catalysis …
contemporary interest, owing to their putative and realized applications in catalysis …
A Combination of Lacunary Polyoxometalates and High‐Nuclear Transition‐Metal Clusters under Hydrothermal Conditions. Part II: From Double Cluster, Dimer, and …
The hydrothermal reactions of trivacant Keggin A‐α‐XW9O34 polyoxoanions (X= PV/SiIV)
with transition‐metal ions (NiII/CuII/FeII) in the presence of amines result in eight novel high …
with transition‐metal ions (NiII/CuII/FeII) in the presence of amines result in eight novel high …
Lanthanide Complexes of the Monovacant Dawson Polyoxotungstate [α1‐P2W17O61]10− as Selective and Recoverable Lewis Acid Catalysts
C Boglio, G Lemière, B Hasenknopf… - Angewandte …, 2006 - Wiley Online Library
Polyoxometalates (POMs) are a large family of metal–oxygen clusters of the early transition
metals in high oxidation states, most commonly VV, MoVI, and WVI.[1] Their intrinsic …
metals in high oxidation states, most commonly VV, MoVI, and WVI.[1] Their intrinsic …
Self-assembly of a series of extended architectures based on polyoxometalate clusters and silver coordination complexes
H An, Y Li, E Wang, D Xiao, C Sun, L Xu - Inorganic chemistry, 2005 - ACS Publications
Three unusual compounds based on polyoxometalate building blocks,[(H2O) 5Na2
(C6NO2H4)(C6NO2H5) 3Ag2][Ag2IMo6O24 (H2O) 4]⊙ 6.25 H2O (1),[(H2O) 4Na2 …
(C6NO2H4)(C6NO2H5) 3Ag2][Ag2IMo6O24 (H2O) 4]⊙ 6.25 H2O (1),[(H2O) 4Na2 …
Octahedron-shaped three-shell Ln 14-substituted polyoxotungstogermanates encapsulating a W 4 O 15 cluster: luminescence and frequency dependent magnetic …
YJ Wang, SY Wu, YQ Sun, XX Li… - Chemical …, 2019 - pubs.rsc.org
A series of new Ln14-substituted polyoxometalates, H27Na16 [(Ln14 (H2O) W4 (OH)
O14)(WO4) 4 (GeW10O38) 6]· nH2O (n≈ 86)(1-Ln, Ln= Eu, Gd, Tb, Dy, Ho, Er), which …
O14)(WO4) 4 (GeW10O38) 6]· nH2O (n≈ 86)(1-Ln, Ln= Eu, Gd, Tb, Dy, Ho, Er), which …
A Gadolinium‐Bridged Polytungstoarsenate(III) Nanocluster: [Gd8As12W124O432(H2O)22]60−
Polyoxometalates (POMs: macromolecular oxoclusters of transition metals in high oxidation
states)[1–3] are unmatched in terms of structural versatility and potential applications in for …
states)[1–3] are unmatched in terms of structural versatility and potential applications in for …
Multicomponent cooperative assembly of nanoscale boron-rich polyoxotungstates with 22 and 30 boron atoms
Y Chen, ZW Guo, XX Li, ST Zheng, GY Yang - CCS Chemistry, 2022 - chinesechemsoc.org
This work demonstrates that the introduction of positive lanthanide (Ln) and transition metal
(TM) cations into polyoxotungstates (POTs) to stabilize negative oxoboron clusters is a …
(TM) cations into polyoxotungstates (POTs) to stabilize negative oxoboron clusters is a …