Combustion chemistry of alkenes and alkadienes

CW Zhou, A Farooq, L Yang, AM Mebel - Progress in Energy and …, 2022 - Elsevier
Alkenes formed, during the refining of crude oil, by cracking the heavier fractions are present
in transportation fuels in significant amounts, up to as much as 15–20% in gasoline …

An overview of the effects of fuel molecular structure on the combustion and emissions characteristics of compression ignition engines

P Hellier, M Talibi, A Eveleigh… - Proceedings of the …, 2018 - journals.sagepub.com
Future fuels for compression ignition engines will be required both to reduce the
anthropogenic carbon dioxide emissions from fossil sources and to contribute to the …

A theoretical calculation and kinetic modeling analysis of H-abstraction from 1-octene for subsequent isomerization and β-dissociation

J Yan, P Wang, T Yan, C Ao, L Zhang, L Lei - International Journal of …, 2024 - Elsevier
As a main component of alkenes, 1-octene is the key important intermediate in the process
of oxidation or pyrolysis of n-decane or higher alkanes. In this work, quantum chemistry …

Experimental and kinetic modeling study of 2-methyl-2-butene: allylic hydrocarbon kinetics

CK Westbrook, WJ Pitz, M Mehl… - The Journal of …, 2015 - ACS Publications
Two experimental studies have been carried out on the oxidation of 2-methyl-2-butene, one
measuring ignition delay times behind reflected shock waves in a stainless steel shock tube …

Structural effects of biodiesel on soot formation in a laminar coflow diffusion flame

MR Kholghy, J Weingarten, AD Sediako, J Barba… - Proceedings of the …, 2017 - Elsevier
Structural effects of biodiesel in terms of unsaturation, ie C= C double bonds, its position and
the presence of the ester moiety on soot formation are studied in this paper. Laminar coflow …

Thermal decomposition of alkenes: role of allylic CC bond cleavage

D Liu, A Farooq - Combustion and Flame, 2024 - Elsevier
Thermal decomposition of alkenes is critical in many chemical processes. In the alkene
moiety, allylic Csingle bondC bonds are significantly weaker than alkylic and vinylic Csingle …

Ignition delay times measurement and kinetic modeling studies of 1-heptene, 2-heptene and n-heptane at low to intermediate temperatures by using a rapid …

Y Wu, Y Liu, C Tang, Z Huang - Combustion and Flame, 2018 - Elsevier
In this work, we have firstly investigated the auto-ignition behaviors of 1-heptene, 2-heptene
and n-heptane in the low to intermediate temperature range (650–950 K) over various …

Experimental and kinetic modeling study of 1-hexene combustion at various pressures

X Fan, G Wang, Y Li, Z Wang, W Yuan, L Zhao - Combustion and Flame, 2016 - Elsevier
The pyrolysis of 1-hexene was studied in a flow reactor by synchrotron vacuum ultraviolet
photoionization mass spectrometry and gas chromatography combined with mass …

Understanding the reactivity of unsaturated alcohols: Experimental and kinetic modeling study of the pyrolysis and oxidation of 3-methyl-2-butenol and 3-methyl-3 …

R De Bruycker, O Herbinet, HH Carstensen… - Combustion and …, 2016 - Elsevier
The reactivity of unsaturated alcohols with a C= C double bond in the β-and γ-positions to
the hydroxyl group is not well established. The pyrolysis and oxidation of two such …

Detailed kinetics of fossil and renewable fuel combustion

CK Westbrook, HJ Curran - Computer Aided Chemical Engineering, 2019 - Elsevier
Chemical kinetic reaction mechanisms for modern combustion systems are described,
including historical highlights and key developments from the past 50 years and evolution of …