3 Advances in the coordination chemistry of amidinate and guanidinate ligands

FT Edelmann - Advances in organometallic chemistry, 2008 - books.google.com
The quest for alternatives to cyclopentadienyl-based ligands has led to a recent renaissance
of N-centered donor ligands in various fields of organometallic and coordination chemistry …

'Old Chemistries' for new applications: Perspectives for development of precursors for MOCVD and ALD applications

A Devi - Coordination chemistry reviews, 2013 - Elsevier
The concept of the transformation of molecules to materials has been well established in the
field of chemical vapor deposition (CVD) and atomic layer deposition (ALD). However …

Metal-containing compound, its production method, metal-containing thin film, and its formation method

K Tada, K Inaba, T Furukawa, T Yamakawa… - US Patent …, 2010 - Google Patents
(57) ABSTRACT A compound which has thermal stability and moderate vapor izability and is
satisfactory as a material for the CVD or ALD method; a process for producing the …

Amidinates, guanidinates and iminopyrrolidinates: Understanding precursor thermolysis to design a better ligand

ST Barry - Coordination Chemistry Reviews, 2013 - Elsevier
The thermolysis of metal compounds incorporating amidinate-type ligands (RN (H) C (X)
NR, where R is any alkyl and X is an alkyl or an amido) show a great complexity and …

Catalytic Addition of Amine N H Bonds to Carbodiimides by Half‐Sandwich Rare‐Earth Metal Complexes: Efficient Synthesis of Substituted Guanidines through …

WX Zhang, M Nishiura, Z Hou - Chemistry–A European Journal, 2007 - Wiley Online Library
Abstract Reaction of [Ln (CH2SiMe3) 3 (thf) 2](Ln= Y, Yb, and Lu) with one equivalent of
Me2Si (C5Me4H) NHR′(R′= Ph, 2, 4, 6‐Me3C6H2, tBu) affords straightforwardly the …

Catalytic addition of alkyne C–H, amine N–H, and phosphine P–H bonds to carbodiimides: an efficient route to propiolamidines, guanidines, and phosphaguanidines

WX Zhang, Z Hou - Organic & Biomolecular Chemistry, 2008 - pubs.rsc.org
Various metal complexes (eg, lanthanides, early transition metals, and alkali metals) can
serve as catalyst precursors for the catalytic addition of alkyne C–H, amine N–H, and …

Mononuclear six-coordinated Ga (III) complexes: A comprehensive survey

G Bandoli, A Dolmella, F Tisato, M Porchia… - Coordination Chemistry …, 2009 - Elsevier
Given the commercial availability of 68Ge–68Ga generators, in principle analogous to the
worldwide utilized 99Mo–99mTc generator, it is surprising that few 68Ga agents have been …

Alkyl aluminum-catalyzed addition of amines to carbodiimides: A highly efficient route to substituted guanidines

WX Zhang, D Li, Z Wang, Z Xi - Organometallics, 2009 - ACS Publications
The commercially readily available alkyl aluminums, such as AlMe3, AlEt3, and AlEt2Cl, can
serve as excellent catalyst precursors for the catalytic addition of amines to carbodiimides …

Hexacoordinated gallium (III) triazenide precursor for epitaxial gallium nitride by atomic layer deposition

P Rouf, R Samii, K Ronnby, B Bakhit… - Chemistry of …, 2021 - ACS Publications
Gallium nitride (GaN) is the main component of modern-day high electron mobility
transistors due to its favorable electronic properties. As electronic devices become smaller …

Synthesis and thermal chemistry of copper (I) guanidinates

JP Coyle, WH Monillas, GPA Yap, ST Barry - Inorganic chemistry, 2008 - ACS Publications
Copper (I) guanidinate dimers were generated by a salt metathesis route and structurally
characterized. The guanidinates differed from the known amidinate dimers because of a …