Alloy negative electrodes for Li-ion batteries

MN Obrovac, VL Chevrier - Chemical reviews, 2014 - ACS Publications
Graphite is an excellent negative electrode (anode) material for Li-ion batteries. It has high
specific capacity (eg,∼ 2.5× higher than LiCoO 2), high volumetric capacity (∼ the same as …

Scanning probe microscopy based characterization of battery materials, interfaces, and processes

R Kempaiah, G Vasudevamurthy, A Subramanian - Nano Energy, 2019 - Elsevier
Increasing demand for sustainable battery technologies has necessitated substantive global
research efforts towards delivering improvements in terms of both, the underlying battery …

Nanoscale mapping of ion diffusion in a lithium-ion battery cathode

N Balke, S Jesse, AN Morozovska, E Eliseev… - Nature …, 2010 - nature.com
The movement of lithium ions into and out of electrodes is central to the operation of lithium-
ion batteries. Although this process has been extensively studied at the device level, it …

Crack pattern formation in thin film lithium-ion battery electrodes

J Li, AK Dozier, Y Li, F Yang… - Journal of The …, 2011 - iopscience.iop.org
Cracking of electrodes caused by large volume change and the associated lithium diffusion-
induced stress during electrochemical cycling is one of the main reasons for the short cycle …

The influence of surface mechanics on diffusion induced stresses within spherical nanoparticles

YT Cheng, MW Verbrugge - Journal of Applied Physics, 2008 - pubs.aip.org
We examine the effects of surface tension and surface modulus on diffusion-induced
stresses within spherical nanoparticles. We show that both the magnitude and distribution of …

Electrochemical stiffness in lithium-ion batteries

H Tavassol, EMC Jones, NR Sottos, AA Gewirth - Nature materials, 2016 - nature.com
Although lithium-ion batteries are ubiquitous in portable electronics, increased charge rate
and discharge power are required for more demanding applications such as electric …

Lithium polyacrylate as a binder for tin–cobalt–carbon negative electrodes in lithium-ion batteries

J Li, DB Le, PP Ferguson, JR Dahn - Electrochimica Acta, 2010 - Elsevier
A lithium polyacrylate (Li-PAA) binder has been developed by 3M Company that is useful
with electrodes comprising alloy anode materials. This binder was used to prepare …

Local probing of ionic diffusion by electrochemical strain microscopy: Spatial resolution and signal formation mechanisms

AN Morozovska, EA Eliseev, N Balke… - Journal of Applied …, 2010 - pubs.aip.org
Electrochemical insertion-deintercalation reactions are typically associated with significant
change in molar volume of the host compound. This strong coupling between ionic currents …

Tin‐based materials as negative electrodes for Li‐ion batteries: combinatorial approaches and mechanical methods

ADW Todd, PP Ferguson… - … Journal of Energy …, 2010 - Wiley Online Library
Graphite has been used as the negative electrode in lithium‐ion batteries for more than a
decade. To attain higher energy density batteries, silicon and tin, which can alloy reversibly …

Stress and strain-energy distributions within diffusion-controlled insertion-electrode particles subjected to periodic potential excitations

MW Verbrugge, YT Cheng - Journal of The Electrochemical …, 2009 - iopscience.iop.org
We derive and implement analytic solutions for the description of insertion particles subject
to cyclic surface concentration variations consistent with a periodic voltage excitation source …