Increasing demand for sustainable battery technologies has necessitated substantive global research efforts towards delivering improvements in terms of both, the underlying battery …
The movement of lithium ions into and out of electrodes is central to the operation of lithium- ion batteries. Although this process has been extensively studied at the device level, it …
Cracking of electrodes caused by large volume change and the associated lithium diffusion- induced stress during electrochemical cycling is one of the main reasons for the short cycle …
We examine the effects of surface tension and surface modulus on diffusion-induced stresses within spherical nanoparticles. We show that both the magnitude and distribution of …
Although lithium-ion batteries are ubiquitous in portable electronics, increased charge rate and discharge power are required for more demanding applications such as electric …
J Li, DB Le, PP Ferguson, JR Dahn - Electrochimica Acta, 2010 - Elsevier
A lithium polyacrylate (Li-PAA) binder has been developed by 3M Company that is useful with electrodes comprising alloy anode materials. This binder was used to prepare …
Electrochemical insertion-deintercalation reactions are typically associated with significant change in molar volume of the host compound. This strong coupling between ionic currents …
ADW Todd, PP Ferguson… - … Journal of Energy …, 2010 - Wiley Online Library
Graphite has been used as the negative electrode in lithium‐ion batteries for more than a decade. To attain higher energy density batteries, silicon and tin, which can alloy reversibly …
MW Verbrugge, YT Cheng - Journal of The Electrochemical …, 2009 - iopscience.iop.org
We derive and implement analytic solutions for the description of insertion particles subject to cyclic surface concentration variations consistent with a periodic voltage excitation source …