Charge transport through molecular ensembles: Recent progress in molecular electronics

Y Liu, X Qiu, S Soni, RC Chiechi - Chemical Physics Reviews, 2021 - pubs.aip.org
This review focuses on molecular ensemble junctions in which the individual molecules of a
monolayer each span two electrodes. This geometry favors quantum mechanical tunneling …

Molecular thermoelectricity in EGaIn-based molecular junctions

J Jang, P He, HJ Yoon - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Understanding the thermoelectric effects that convert energy between heat and
electricity on a molecular scale is of great interest to the nanoscience community. As …

Thiol-free self-assembled oligoethylene glycols enable robust air-stable molecular electronics

X Qiu, V Ivasyshyn, L Qiu, M Enache, J Dong… - Nature Materials, 2020 - nature.com
Self-assembled monolayers (SAMs) are widely used to engineer the surface properties of
metals. The relatively simple and versatile chemistry of metal–thiolate bonds makes thiolate …

Strain sensors fabricated by surface assembly of nanoparticles

HW Cheng, S Yan, G Shang, S Wang… - Biosensors and …, 2021 - Elsevier
Harnessing interparticle spatial properties of surface assembly of nanoparticles (SAN) on
flexible substrates is a rapidly emerging front of research in the design and fabrication of …

Decoding the mechanical conductance switching behaviors of dipyridyl molecular junctions

F Sun, L Liu, CF Zheng, YC Li, Y Yan, XX Fu, CK Wang… - Nanoscale, 2023 - pubs.rsc.org
Dipyridyl molecular junctions often show intriguing conductance switching behaviors with
mechanical modulations, but the mechanisms are still not completely revealed. By applying …

Self-Assembly Determines Sign of Seebeck Coefficient in Tunneling Junctions Comprising Monolayers and Bilayers of Fullerenes

CL Mthembu, RC Chiechi - Nano Letters, 2024 - ACS Publications
We measured the Seebeck coefficient for junctions comprising self-assembled monolayers
and bilayers of the fullerene moiety PTEG-1 on Au using eutectic Ga–In in a controlled …

N-heterocyclic carbenes for the self-assembly of thin and highly insulating monolayers with high quality and stability

A Krzykawska, M Wróbel, K Kozieł, P Cyganik - ACS nano, 2020 - ACS Publications
As an organic nanostructure, self-assembled monolayers (SAMs) play a central role in many
aspects of nanotechnology, including molecular electronics. In this work, we show that SAMs …

Why one can expect large rectification in molecular junctions based on alkane monothiols and why rectification is so modest

Z Xie, I Bâldea, CD Frisbie - Chemical Science, 2018 - pubs.rsc.org
Many attempts to obtain high current rectification ratios (RRs) in molecular electronics are
triggered by a potentiometer rule argument, which predicts that a strongly asymmetric …

In Operando Modulation of Rectification in Molecular Tunneling Junctions Comprising Reconfigurable Molecular Self‐Assemblies

X Qiu, S Rousseva, G Ye, JC Hummelen… - Advanced …, 2021 - Wiley Online Library
The reconfiguration of molecular tunneling junctions during operation via the self‐assembly
of bilayers of glycol ethers is described. Well‐established functional groups are used to …

A single atom change turns insulating saturated wires into molecular conductors

X Chen, B Kretz, F Adoah, C Nickle, X Chi, X Yu… - Nature …, 2021 - nature.com
We present an efficient strategy to modulate tunnelling in molecular junctions by changing
the tunnelling decay coefficient, β, by terminal-atom substitution which avoids altering the …