Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Seeing the light: advancing materials chemistry through photopolymerization

N Corrigan, J Yeow, P Judzewitsch… - Angewandte Chemie …, 2019 - Wiley Online Library
The application of photochemistry to polymer and material science has led to the
development of complex yet efficient systems for polymerization, polymer post …

Photo‐iniferter RAFT polymerization

M Hartlieb - Macromolecular Rapid Communications, 2022 - Wiley Online Library
Light‐mediated polymerization techniques offer distinct advantages over polymerization
reactions fueled by thermal energy, such as high spatial and temporal control as well as the …

PET-RAFT polymerization: Mechanistic perspectives for future materials

ML Allegrezza, D Konkolewicz - ACS Macro Letters, 2021 - ACS Publications
In the past decade, photochemistry has emerged as a growing area in organic and polymer
chemistry. Use of light to drive polymerization has advantages by imparting spatial and …

Photoinitiated Polymerization‐Induced Self‐Assembly (Photo‐PISA): New Insights and Opportunities

J Yeow, C Boyer - Advanced Science, 2017 - Wiley Online Library
The polymerization‐induced self‐assembly (PISA) process is a useful synthetic tool for the
efficient synthesis of polymeric nanoparticles of different morphologies. Recently, studies on …

The emergence of reversible–deactivation radical polymerization in 3D printing

VA Bobrin, J Zhang, N Corrigan… - Advanced Materials …, 2023 - Wiley Online Library
The majority of materials 3D printed using vat photopolymerization techniques are prepared
by uncontrolled polymerization methods and cannot be easily modified to introduce …

Recent advances on photobleachable visible light photoinitiators of polymerization

F Dumur - European Polymer Journal, 2023 - Elsevier
Photopolymerization under visible light has known major breakthroughs in recent years due
to the development of new irradiation setups based on Light-Emitting Diodes (LEDs) …

Oxygen tolerant photopolymerization for ultralow volumes

J Yeow, R Chapman, J Xu, C Boyer - Polymer Chemistry, 2017 - pubs.rsc.org
A benchtop approach is developed for the synthesis of various polymeric architectures using
an aqueous Reversible Addition–Fragmentation chain Transfer (RAFT) photopolymerization …

Organic dye‐based photoinitiating systems for visible‐light‐induced photopolymerization

K Sun, P Xiao, F Dumur… - Journal of Polymer Science, 2021 - Wiley Online Library
Even though many organic dyes have been reported as photoinitiators/photosensitizers for
free radical polymerization in the literature, the design and development of novel …

Color-coding visible light polymerizations to elucidate the activation of trithiocarbonates using eosin Y

CA Figg, JD Hickman, GM Scheutz… - …, 2018 - ACS Publications
We report mechanistic investigations into aqueous visible-light reversible addition–
fragmentation chain transfer (RAFT) polymerizations of acrylamides using eosin Y as a …