Molecular catalysts for CO2 Electroreduction: Progress and prospects with pincer type complexes

HA Younus, N Ahmad, W Ni, X Wang, M Al-Abri… - Coordination Chemistry …, 2023 - Elsevier
Transforming wastes or hazardous materials into value-added chemical products is of great
concern from economic, environmental, and sustainable prospects. Various approaches …

Self-assembled chromophore–catalyst bilayer for water oxidation in a dye-sensitized photoelectrosynthesis cell

D Wang, L Wang, MD Brady, CJ Dares… - The Journal of …, 2019 - ACS Publications
A new approach is described here for the preparation of water-oxidation photoanodes in a
dye-sensitized photoelectrosynthesis cell for water splitting. It is based on a chromophore …

Charge‐transfer character in a covalent diketopyrrolopyrrole dimer: implications for singlet fission

CM Mauck, YJ Bae, M Chen, N Powers‐Riggs… - …, 2018 - Wiley Online Library
Diketopyrrolopyrrole (DPP) is a strongly absorbing, photostable chromophore that can
undergo singlet fission (SF), a photophysical process that promises to significantly enhance …

1, 7, 9, 10‐Tetrasubstituted PMIs Accessible through Decarboxylative Bromination: Synthesis, Characterization, Photophysical Studies, and Hydrogen Evolution …

D Costabel, A Skabeev, A Nabiyan… - … A European Journal, 2021 - Wiley Online Library
In this work, we present a new synthetic strategy for fourfold‐substituted perylene
monoimides via tetrabrominated perylene monoanhydrides. X‐ray diffraction analysis …

Chelated [Zn (cyclam)] 2+ Lewis acid improves the reactivity of the electrochemical reduction of CO 2 by Mn catalysts with bulky bipyridine ligands

A Zhanaidarova, H Steger, MH Reineke… - Dalton …, 2017 - pubs.rsc.org
This communication reports the use of a soluble Lewis acid complex,[Zn (cyclam)]
2+(cyclam= 1, 4, 8, 11-tetraazacyclotetradecane) as a co-catalyst coupled with Mn …

Four-and five-coordinate nickel (ii) complexes bearing new diphosphine–phosphonite and triphosphine–phosphite ligands: catalysts for N-alkylation of amines

D Panigrahi, M Mondal, R Gupta, G Mani - RSC advances, 2022 - pubs.rsc.org
The reaction of Ph2PCH2OH with PhPCl2 and PCl3 in the presence of Et3N afforded new
phosphonite compounds PhP (OCH2PPh2) 2 1 and P (OCH2PPh2) 3 2, respectively. The …

Quantum chemistry of the excited state: recent trends in methods developments and applications

M Navarrete-Miguel, J Segarra-Martí… - 2018 - books.rsc.org
Advances (2016–2017) in Quantum Chemistry of the Excited State (QCEX) are presented in
this book chapter focusing firstly on developments of methodology and excited-state reaction …

Modifying the steric and electronic character within Re (I)-phenanthroline complexes for electrocatalytic CO2 reduction

BJ Neyhouse, TA White - Inorganica Chimica Acta, 2018 - Elsevier
We have synthesized and characterized a series of fac-[Re (R 2 phen)(CO) 3 Cl] complexes
(R 2 phen= 2, 9-disubstituted-1, 10-phenanthroline) that function as electrocatalysts for the …

Sequential Electrophilic Substitution Reactions of Tungsten-Coordinated Phosphenium Ions and Phosphine Triflates

A Jayaraman, S Nilewar, TV Jacob, BT Sterenberg - ACS omega, 2017 - ACS Publications
Abstraction of chloride from [W (CO) 5 {PPhCl2}] with AgOSO2CF3 leads to the phosphine
triflate complex [W (CO) 5 {PPhCl (OSO2CF3)}] which undergoes electrophilic substitution …

Efficient palladium (II) electrocatalysts with thiophene anchored pyridinium amidates for CO2 reduction

MZ Idrees, I Ilahi, MZ Ali, Z Muhammad - Journal of CO2 Utilization, 2021 - Elsevier
Palladium (II) complexes namely [Pd (L Me) 2 (Cl) 2](5),[Pd (L Et) 2 (Cl) 2](6),[Pd (L Bu)(Cl)
2](7) and [Pd (L Bz)(Cl) 2](8) were synthesized as electrocatalysts towards CO 2 reduction …