Palladium-catalyzed coupling reactions have become a powerful tool in organic synthesis. 1
Today, there are numerous applications of palladium catalysts in the preparation of …

The transformation of C H bonds into other chemical bonds is of great significance in
synthetic chemistry. C H bond‐activation processes provide a straightforward and atom …

The C–N cross-coupling chemistry intensely developed since the late 1990s has supplied
synthesists with an overwhelming number of methods to effectively combine carbon and …

A transition-metal-free synthetic method has been developed for the synthesis of
unsymmetrical diaryl chalcogenides (S, Se, and Te) from diaryl dichalcogenides and arenes …

The first example of the enantioselective methyl C–H activation by an intramolecular ArPdX
species and subsequent cyclisation was developed. Palladium catalysts using commercially …

Palladium-catalyzed oxidative carbonylation of N-sulfonyl-2-aminobiaryls through C–H bond
activation and C–C, C–N bond formation under TFA-free and milder conditions has been …

The palladium-catalyzed cyclization on the fullerene C60 cage has been achieved using
several aryl halides and C60. This reaction was found to be accelerated by the addition of …

A novel and efficient Cu (I)-catalyzed radical heteroannulation reaction of [60] fullerene
(C60) with α-bromo acetamides has been disclosed for the direct synthesis of diverse C60 …

Functionalization with the sulfonic acid group as the directing group in a C–H activation
reaction has been revealed for the first time.[60] Fullerene has been employed in the …

A cuprous bromide-catalyzed heteroannulation reaction of [60] fullerene with ketoxime
acetates has been exploited to prepare novel 1-fulleropyrrolines through the cleavage of N …