Enroute sustainability: metal free C–H bond functionalisation

S Roy, S Panja, SR Sahoo, S Chatterjee… - Chemical Society …, 2023 - pubs.rsc.org
The term “C–H functionalisation” incorporates C–H activation followed by its transformation.
In a single line, this can be defined as the conversion of carbon–hydrogen bonds into …

Recent developments in the synthesis of imidazo [1, 2-a] pyridines

K Pericherla, P Kaswan, K Pandey, A Kumar - Synthesis, 2015 - thieme-connect.com
Advances in the last decade for the synthesis of the imidazo [1, 2-a] pyridine scaffold from
various substrates employing approaches such as multicomponent reactions, tandem …

Tunable Electrochemical C− N versus N− N Bond Formation of Nitrogen‐Centered Radicals Enabled by Dehydrogenative Dearomatization: Biological Applications

S Lv, X Han, JY Wang, M Zhou, Y Wu… - Angewandte Chemie …, 2020 - Wiley Online Library
Herein, an environmentally friendly electrochemical approach is reported that takes
advantage of the captodative effect and delocalization effect to generate nitrogen‐centered …

Accelerated photochemical reactions at oil-water interface exploiting melting point depression

YM Tian, W Silva, RM Gschwind, B König - Science, 2024 - science.org
Water can accelerate a variety of organic reactions far beyond the rates observed in
classical organic solvents. However, using pure water as a solvent introduces solubility …

Electrophilic C–H Borylation of Aza [5] helicenes Leading to Bowl-Shaped Quasi-[7] Circulenes with Switchable Dynamics

X Zhang, F Rauch, J Niedens, RB da Silva… - Journal of the …, 2022 - ACS Publications
The intrinsic relationship between helicenes and circulenes is of fundamental interest and
importance in molecular engineering. Herein, electrophilic borylation of phenanthroline …

Iodine-catalyzed regioselective thiolation of imidazo [1, 2-a] pyridines using sulfonyl hydrazides as a thiol surrogate

AK Bagdi, S Mitra, M Ghosh, A Hajra - Organic & Biomolecular …, 2015 - pubs.rsc.org
Iodine-catalyzed regioselective sulfenylation of imidazo [1, 2-a] pyridines via C (sp2)–H
bond functionalization has been achieved using sulfonyl hydrazides as a thiol surrogate. A …

Recent Advances in the Synthesis of Imidazo[1,2‐a]pyridines: A Brief Review

J Panda, BP Raiguru, M Mishra, S Mohapatra… - …, 2022 - Wiley Online Library
This review focuses on providing comprehensive highlights of the recent synthetic pathways
of imidazo [1, 2‐a] pyridines, assisted through transition metal‐catalyzed reactions, multi …

Construction of N-containing heterocycles via oxidative intramolecular N–H/X–H coupling

J Yuan, C Liu, A Lei - Chemical Communications, 2015 - pubs.rsc.org
The preparation of N-containing heterocycles is always the core of synthetic chemistry.
Recently, oxidative coupling between two R–H nucleophiles is gaining more attention due to …

Recent Advances in Intramolecular Metal‐Free Oxidative C–H Bond Aminations Using Hypervalent Iodine (III) Reagents

S Reddy Kandimalla… - European Journal of …, 2019 - Wiley Online Library
Hypervalent iodine chemistry is a rapidly growing area of research with tremendous impact
on synthetic chemistry in the past years. A rich and diverse chemistry is now available for …

Copper-catalyzed inter-and intramolecular C–N bond formation: synthesis of benzimidazole-fused heterocycles

S Rasheed, DN Rao, P Das - The Journal of Organic Chemistry, 2015 - ACS Publications
A Cu (II)-catalyzed, inter/intramolecular C–N bond formation for the synthesis of various
benzimidazole-fused heterocycles in a concise manner has been reported. The robustness …