Carbohydrates, which are ubiquitously distributed throughout the three domains of life, play
significant roles in a variety of vital biological processes. Access to unique and …

Sulfoxides have emerged as pivotal constituents in modern carbohydrate chemistry. As
anomeric leaving groups, sulfinyl moieties may occupy positions directly at the anomeric …

A novel one-pot relay glycosylation has been established. The protocol is characterized by
the construction of two glycosidic bonds with only one equivalent of triflic anhydride. This …

Pseudaminic acid is an amino deoxy sialic acid whose glycosides are essential components
of many pathogenic Gram-negative bacterial cell walls including those from Pseudomonas …

Although numerous glycosylation methods have been developed for the construction of
glycosidic bonds, the pace of discovering rapid assembly strategies to access complex …

Two classes of thioglycoside, 4-(4-methoxyphenyl)-3-butenylthioglycosides (MBTGs) and 4-
(4-methoxyphenyl)-4-pentenylthioglycosides (MPTGs), undergo acid-catalyzed O …

4-(p-Methoxyphenyl)-4-pentenylthioglycosides (MPTGs) undergo acid-catalyzed O-
glycosylation with a range of alcohol acceptors in the presence of 10 mol% of triflic acid at …

The S-indolyl (SIn) anomeric moiety was investigated as a new leaving group that can be
activated for chemical glycosylation under a variety of conditions including thiophilic and …

Gold-catalyzed synthesis of α-D-glucosides using an o-ethynylphenyl β-D-1-thioglucoside donor
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A mild glycosylation protocol is developed by using glycosyl 1‐methylimidazole‐2‐
carboxylates. Such a glycosylation can be promoted by a series of metal triflates and …