Two-dimensional metallacycles and three-dimensional metallacages constructed by
coordination-driven self-assembly have attracted much attention because they exhibit …

Conspectus For the last two decades, materials scientists have contributed to a growing
library of porous crystalline materials. These synthetic materials are typically extended …

Coordination-driven self-assembly enables the spontaneous construction of metallo-
supramolecules with high precision, facilitated by dynamic and reversible metal–ligand …

The porous coordination cage PCC-1 represents a new platform potentially useful for the
cellular delivery of drugs with poor cell permeability and solubility. PCC-1 is a metal–organic …

Despite their well-defined and intrinsic porous structures, metal–organic cages (MOCs)
readily lose their crystalline arrangement upon solvent exchange and desolvation, which …

Zirconium-based metal–organic polyhedra (ZrMOPs) are attractive due to their high
stabilities, low-cost building blocks, and solubilities relative to their metal–organic framework …

Although the fundamental configuration (tetrahedron-type and capsule-type) of Zr-MOCs is
well understood, the synthesis of amino-functionalized Zr-based capsule (denoted as ZrC-1 …

Energy-efficient capture and release of small gas molecules, particularly carbon dioxide
(CO2) and methane (CH4), are of significant interest in academia and industry. Porous …

Metal–organic cage‐based photo‐responsive supramolecular frameworks (PSMFs) with
permanent porosity have gained attention for their modular properties, controllable …

In this study, we scrutinized the self-assembly dynamics of mixed-ligand MOCs employing
HR-MS. Our findings unveiled the remarkable coexistence of tetrahedron and cigar …