O–O bond formation mechanisms during the oxygen evolution reaction over synthetic molecular catalysts

XP Zhang, HY Wang, H Zheng, W Zhang… - Chinese Journal of …, 2021 - Elsevier
Water oxidation is one of the most important reactions in natural and artificial energy
conversion schemes. In nature, solar energy is converted to chemical energy via water …

The genesis of molecular volcano plots

MD Wodrich, B Sawatlon, M Busch… - Accounts of chemical …, 2021 - ACS Publications
Conspectus For the past two decades, linear free energy scaling relationships and volcano
plots have seen frequent use as computational tools that aid in understanding and …

Catalysis of a single transition metal site for water oxidation: from mononuclear molecules to single atoms

H Zhang, W Tian, X Duan, H Sun, S Liu… - Advanced …, 2020 - Wiley Online Library
Low‐cost, nonprecious transition metal (TM) catalysts toward efficient water oxidation are of
critical importance to future sustainable energy technologies. The advances in structure …

Mononuclear first-row transition-metal complexes as molecular catalysts for water oxidation

N Wang, H Zheng, W Zhang, R Cao - Chinese Journal of Catalysis, 2018 - Elsevier
Water oxidation is significant in both natural and artificial photosynthesis. In nature, water
oxidation occurs at the oxygen-evolving center of photosystem II, and leads to the …

Insight into the photocatalytic activity of cobalt-based metal–organic frameworks and their composites

A Ejsmont, A Jankowska, J Goscianska - Catalysts, 2022 - mdpi.com
Nowadays, materials with great potential for environmental protection are being sought.
Metal–organic frameworks, in particular those with cobalt species as active sites, have …

Redox-active ligand assisted electrocatalytic water oxidation by a mononuclear cobalt complex

S Biswas, S Bose, J Debgupta, P Das… - Dalton Transactions, 2020 - pubs.rsc.org
In this report, the synthesis, characterization and electrocatalytic oxidation of water by a
mononuclear cobalt (III) complex,[CoIII (dpaq)(Cl)] Cl (1) featuring a redox-active …

Scaling relationships and volcano plots in homogeneous catalysis

M Anand, B Rohr, MJ Statt… - The Journal of Physical …, 2020 - ACS Publications
Scaling relations and volcano plots are widely used in heterogeneous catalysis. In this
Perspective, we discuss the prospects and challenges associated with the application of …

Molecular Nature of Electrodeposits in Electrochemical Water Oxidation

HA Younus, N Ahmad, M Al‐Abri… - Advanced Energy …, 2023 - Wiley Online Library
The molecular nature and the structure of the real catalyst are matters of serious concern in
homogeneous catalysis. Catalyst transformation in molecular water oxidation catalysis …

Computational modeling of cobalt-based water oxidation: current status and future challenges

M Schilling, S Luber - Frontiers in chemistry, 2018 - frontiersin.org
A lot of effort is nowadays put into the development of novel water oxidation catalysts. In this
context, mechanistic studies are crucial in order to elucidate the reaction mechanisms …

Exploring the limitation of molecular water oxidation catalysts

M Busch, A Fabrizio, S Luber, J Hutter… - The Journal of …, 2018 - ACS Publications
Linear free energy scaling relationships (LFESRs) and volcano plots are routinely used to
assess the performance of heterogeneous electrocatalysts and have only recently been …