Two borane-functionalized bidentate phosphine ligands that vary in tether length have been
prepared to examine cooperative metal–substrate interactions. Ni (0) complexes react with …

Heterocycles containing group 13 and 15 elements such as borazines are an integral part of
organic, biomedical and materials chemistry. Surprisingly, heterocycles containing P and Al …

Metal‐ligand cooperation has emerged as a versatile tool for substrate activation in
chemical reactivity. Herein, we provide the synthesis and characterization of a monoboranyl …

Diphosphines have taken on a dominant role as supporting ligands in transition-metal
chemistry. Here, we describe complexes of the type [Cp* Fe (diphosphine)(X)](X= Cl, H) …

The catalytic conversion of unsaturated small molecules such as nitriles into reduced
products is of interest for the production of fine chemicals. In this vein, metal–ligand …

The incorporation of boron functionalities into transition-metal catalysts has become a
promising strategy to improve catalytic performance, although their synthesis typically entails …

Secondary coordination sphere ligand effects can be used to direct or organize small
molecule substrates at a metal center. Herein, we assess the bifunctional ambiphilic …

Whereas k3-P, C, P-based donor ligands are ubiquitous across synthetic chemistry, related
unsymmetric systems having 3-P, P, C-coordination are comparatively rare. In this …

In developing homogenous catalysts capable of CO2 activation, interaction with a metal
center is often imperative. This work provides primary efforts towards the cooperative …

Abstract Heterocyclen, die Elemente der Gruppen 13 und 15 enthalten, wie z. B. Borazine,
sind ein fester Bestandteil der organischen, biomedizinischen und Materialchemie …