Beginning as chemical curiosities with the pioneering work of Curtius, 1a Staudinger, 1b and
even earlier efforts, 1c carbenes have played an important role as transient intermediates …

The success of homogeneous catalysis can be attributed largely to the development of a
diverse range of ligand frameworks that have been used to tune the behavior of various …

Over two decades have passed since the fifth edition of Phosphorus: Chemistry,
Biochemistry and Technology. Major advances in chemistry, materials science, electronics …

Carbenes are neutral compounds featuring a divalent carbon atom. Their rich reactivity both
as naked species and within complexes of transition metals has allowed for spectacular …

Abstract Der Erfolg der homogenen Katalyse kann hauptsächlich der Entwicklung einer
breiten Palette von Ligandengerüsten zugeschrieben werden, die vielfach genutzt wurden …

It is that up'-biscarbenes, generated from the corresponding bisdiazo derivatives 1 b, are
stable compounds; however, from their reactivity they must be regarded as alkynes rather …

Organophosphorus compounds have been applied in two ways in chemical synthesis. They
can either be used as a reagent in a step of the synthesis (for example, in the Wittig reaction) …

Investigation of unstable and metastable compounds is a basis for the development of many
highpriority branches of modern chemistry, among which we find the recent emergence of …

Organophosphorverbindungen werden auf zweierlei Art in der Synthesechemie eingesetzt:
Entweder dienen sie als Hilfsreagentien wie etwa bei der Wittig‐Reaktion, oder sie werden …

The carbon–carbon triple bond I is a ubiquitous functional group in organic chemistry.[1] In
marked contrast, the chemistry of heavier derivatives with triple bonds to silicon has only …