Octacyanidometallates for multifunctional molecule-based materials

S Chorazy, JJ Zakrzewski, M Magott… - Chemical Society …, 2020 - pubs.rsc.org
Octacyanidometallates have been successfully employed in the design of heterometallic
coordination systems offering a spectacular range of desired physical properties with great …

Photomagnetism in cyano-bridged bimetal assemblies

S Ohkoshi, H Tokoro - Accounts of chemical research, 2012 - ACS Publications
The study of photoinduced phase-transition materials has implications for the fields of
inorganic chemistry, solid-state chemistry, and materials science. Cyano-bridged bimetal …

Light-induced spin-crossover magnet

S Ohkoshi, K Imoto, Y Tsunobuchi, S Takano… - Nature …, 2011 - nature.com
The light-induced phase transition between the low-spin (LS) and high-spin (HS) states of
some transition-metal ions has been extensively studied in the fields of chemistry and …

Novel magnetic functionalities of Prussian blue analogs

H Tokoro, S Ohkoshi - Dalton Transactions, 2011 - pubs.rsc.org
Cyano-bridged bimetal assemblies demonstrate novel magnetic functionalities, particularly
Prussian blue analogs, which have unique properties. In this perspective, we describe a …

The impact of ligands upon topology and functionality of octacyanidometallate-based assemblies

B Nowicka, T Korzeniak, O Stefańczyk… - Coordination Chemistry …, 2012 - Elsevier
Complete overview of octacyanidometallate polymetallic assemblies is presented from a
novel viewpoint of the importance of incorporated ligands. The ligands are classified …

Photoinduced Magnetization with a High Curie Temperature and a Large Coercive Field in a Co‐W Bimetallic Assembly

N Ozaki, H Tokoro, Y Hamada, A Namai… - Advanced Functional …, 2012 - Wiley Online Library
The crystal structure, magnetic properties, and temperature‐and photoinduced phase
transition of [{CoII (4‐methylpyridine)(pyrimidine)} 2 {CoII (H2O) 2}{WV (CN) 8} 2]· 4H2O are …

Multifunctional Magnetic Molecular {[MnII(urea)2(H2O)]2[NbIV(CN)8]}n System: Magnetization-Induced SHG in the Chiral Polymorph

D Pinkowicz, R Podgajny, W Nitek, M Rams… - Chemistry of …, 2011 - ACS Publications
Incorporation of urea molecules into the magnetic system MnII-[NbIV (CN) 8] results in
formation of two magnetic polymorphs {[MnII (H2O)(urea) 2] 2 [NbIV (CN) 8]} n chiral α and …

Towards multifunctional magnetic systems through molecular-programmed self assembly of Re (IV) metalloligands

J Martinez-Lillo, J Faus, F Lloret, M Julve - Coordination Chemistry Reviews, 2015 - Elsevier
The molecular-programmed approach based on the use as ligands of tailor-made
metalloligands containing stable six-coordinate rhenium (IV) as paramagnetic centres is …

New family of thiocyanate-bridged Re (IV)-SCN-M (II)(M= Ni, Co, Fe, and Mn) heterobimetallic compounds: synthesis, crystal structure, and magnetic properties

R Gonzalez, A Acosta, R Chiozzone, C Kremer… - Inorganic …, 2012 - ACS Publications
The heterobimetallic complexes of formula [(Me2phen) 2M (μ-NCS) Re (NCS) 5]· CH3CN
[Me2phen= 2, 9-dimethyl-1, 10-phenanthroline and M= Ni (1), Co (2), Fe (3), and Mn (4)] …

Nature of Magnetic Interactions in 3D {[MII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (M = Mn, Fe, Co, Ni) Molecular Magnets

D Pinkowicz, R Pełka, O Drath, W Nitek… - Inorganic …, 2010 - ACS Publications
The self-assembly of [NbIV (CN) 8] 4− with different 3d metal centers in an aqueous solution
and an excess of pyrazole resulted in the formation of four 3D isostructural compounds {[MII …