[HTML][HTML] State-of-the-Art Review of Oxidative Dehydrogenation of Ethane to Ethylene over MoVNbTeOx Catalysts

Y Chen, B Yan, Y Cheng - Catalysts, 2023 - mdpi.com
Ethylene is mainly produced by steam cracking of naphtha or light alkanes in the current
petrochemical industry. However, the high-temperature operation results in high energy …

Cobalt-molybdenum oxides for effective coupling of ethane activation and carbon dioxide reduction catalysis

R Yao, J Pinals, R Dorakhan, JE Herrera, M Zhang… - ACS …, 2022 - ACS Publications
This study reports the discovery of CoMoO x moieties with synergistic catalytic roles in C2H6–
CO2 catalysis. C2H6–CO2 catalysis occurs through multiple, concomitant catalytic cycles …

Propane Dehydrogenation on PtxZny Active Sites in Silicalite‐1

Y Liu, A Bhowmick, D Liu… - Angewandte Chemie …, 2024 - Wiley Online Library
The improvement of Pt‐based catalysts for propane dehydrogenation (PDH) has progressed
by recent investigations that have identified Zn as a promising promoter for Pt subnanometer …

Quantum Chemical Modeling of the Full Catalytic Cycle for Selective Oxidation of Propane to Propene on the M1 Phase of Mo–Te–Nb–O Mixed-Metal Oxide Catalysts

K Sen, A Schäfer, F Rosowski… - The Journal of …, 2024 - ACS Publications
In this work, we have performed a quantum chemical study for the selective oxidation of
propane to propene on the M1 phase of a mixed-metal oxide catalyst, consisting of Mo–Nb …

Identification of the intrinsic active site in phase-pure M1 catalysts for oxidation dehydrogenation of ethane by density functional theory calculations

S Qian, Y Chen, Y Wang, B Yan… - The Journal of Physical …, 2022 - ACS Publications
Heterogeneous catalysts for alkane conversion reactions are required to possess both high
activity for C–H bond cleavage and selectivity to target products. This work employed an …

A global kinetic model for the oxidative dehydrogenation of ethane over mixed metal oxide catalysts at supra-ambient pressures

J Chen, Z Sun, V Balakotaiah, P Bollini - Chemical Engineering Journal, 2022 - Elsevier
Oxidative dehydrogenation of ethane (ODHE), unlike traditional steam cracking processes,
can potentially be used to produce ethene at supra-ambient pressures, thereby reducing …

Surface engineering of TeOx modification on MoVTeNbO creates a high-performance catalyst for oxidation of toluene homologues to aldehydes

C Deng, B Ge, J Yao, T Zhao, C Shen, Z Zhang… - Chinese Journal of …, 2024 - Elsevier
The heterogeneous catalytic oxidation of toluene by O 2 is an inherently safe and green
route for production of benzaldehyde, but after more than fifty years of effort, it remains a …

Effects of surface species and homogeneous reactions on rates and selectivity in ethane oxidation on oxide catalysts

Y Liu, CJ McGill, WH Green, P Deshlahra - AIChE Journal, 2021 - Wiley Online Library
Selective alkane oxidations on metal oxide catalysts involve complex mechanisms with
multiple reactions in series and parallel, different types of reduced and oxidized surface …

Mechanistic framework and effects of high coverage in vinyl acetate synthesis

Z Zha, P Deshlahra - ACS Catalysis, 2021 - ACS Publications
Solid catalysts often operate at high surface coverage, but fully analyzing and leveraging
coverage effects remains challenging. Vinyl acetate (VA) synthesis via oxidatively …

Nb− V mixed oxide with a random assembly of pentagonal units: a catalyst for oxidative dehydrogenation of ethane and propane

K Shimoda, S Ishikawa, K Matsumoto… - …, 2021 - Wiley Online Library
High‐dimensionally structured (HDS) mixed oxides of vanadium with metals (M)(eg, Nb, Mo,
and W; denoted as HDS‐MVO) were constructed by {M6O21} 12− pentagonal units and …