Determining the key vibrations for spin relaxation in ruffled Cu (II) porphyrins via resonance Raman spectroscopy

NP Kazmierczak, NE Lopez, KM Luedecke… - Chemical Science, 2024 - pubs.rsc.org
Pinpointing vibrational mode contributions to electron spin relaxation (T1) constitutes a key
goal for developing molecular quantum bits (qubits) with long room-temperature coherence …

Coherent spin-control of S= 1 vanadium and molybdenum complexes

DW Laorenza, KR Mullin, LR Weiss, SL Bayliss… - Chemical …, 2024 - pubs.rsc.org
The burgeoning field of quantum sensing hinges on the creation and control of quantum bits.
To date, the most well-studied quantum sensors are optically active, paramagnetic defects …

Ligand field design enables quantum manipulation of spins in Ni 2+ complexes

MK Wojnar, K Kundu, A Kairalapova, X Wang… - Chemical …, 2024 - pubs.rsc.org
Creating the next generation of quantum systems requires control and tunability, which are
key features of molecules. To design these systems, one must consider the ground-state and …

Elucidating ultranarrow 2 F 7/2 to 2 F 5/2 absorption in ytterbium (iii) complexes

BY Li, CE Dickerson, AJ Shin, C Zhao, Y Shen… - Chemical …, 2024 - pubs.rsc.org
Achieving ultranarrow absorption linewidths in the condensed phase enables optical state
preparation of specific non-thermal states, a prerequisite for quantum-enabled technologies …