The strength of the macromonomer strategy for complex macromolecular architecture: Molecular characterization, properties and applications of polymacromonomers

N Hadjichristidis, M Pitsikalis, H Iatrou… - Macromolecular rapid …, 2003 - Wiley Online Library
The efficiency of the macromonomer (MM) synthetic strategy for the creation of nonlinear
complex macromolecular architectures (miktoarm stars, α, ω‐branched polymers …

Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization

T Pan, S Dutta, Y Kamble, BB Patel… - Chemistry of …, 2022 - ACS Publications
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …

Research progress on the conformational properties of comb-like polymers in dilute solutions

M Zhu, X Pan, T Zheng, L Li - Soft Matter, 2024 - pubs.rsc.org
As a special type of branched polymers, comb-like polymers simultaneously possess the
structural characteristics of a linear backbone profile and crowded sidechain …

Conformation of cylindrical brushes in solution: effect of side chain length

B Zhang, F Gröhn, JS Pedersen, K Fischer… - …, 2006 - ACS Publications
The conformation of cylindrical brush polymers with a polymethacrylate main and
polystyrene side chains (6≤≤ 33, with the number-average degree of polymerization of the …

Bridging simulation length scales of bottlebrush polymers using a wormlike cylinder model

S Dutta, T Pan, CE Sing - Macromolecules, 2019 - ACS Publications
Bottlebrush polymers, formed from a linear backbone polymer with a high density of grafted
side chains, are functional macromolecules useful in molecular assembly and responsive …

Radius of gyration of polystyrene combs and centipedes in solution

Y Nakamura, Y Wan, JW Mays, H Iatrou… - …, 2000 - ACS Publications
The method of Iatrou et al.(Macromolecules 1998, 31, 6697) was applied to synthesize a
normal comb polystyrene sample with uniform side chains equally spaced along the main …

Solution properties of polymacromonomers consisting of polystyrene V. Effect of side chain length on chain stiffness

T Hokajo, K Terao, Y Nakamura, T Norisuye - Polymer journal, 2001 - nature.com
Light scattering and viscosity measurements were made on cyclohexane and toluene
solutions of a series of polymacromonomer samples consisting of polystyrene with 65 …

Backbone stiffness of comb-branched polymers

Y Nakamura, T Norisuye - Polymer journal, 2001 - nature.com
The free energy change accompanying the bending of the main chain of a comb-branched
polymer is evaluated in terms of excluded-volume interactions among side chains to obtain λ …

Two stretching regimes in the elasticity of bottlebrush polymers

S Dutta, CE Sing - Macromolecules, 2020 - ACS Publications
The elasticity of highly branched polymers, known as bottlebrush polymers, is integral to
understanding their physical properties in a wide variety of applications; bottlebrush …

Simulation and Analysis of Molecular Bottlebrush Dynamics in Dilute Solutions

RS Mukkamala, MJA Hore - Macromolecules, 2024 - ACS Publications
Molecular bottlebrushes consist of a linear polymer backbone that is densely grafted with
side chains. They have received considerable attention due to their unique physical …