The chemical and physical properties of tetravalent lanthanides: Pr, Nd, Tb, and Dy
The fundamental redox chemistry and valence electronic structure of the lanthanides in
molecular complexes and extended solids continues to be a fertile area of research. The …
molecular complexes and extended solids continues to be a fertile area of research. The …
Chemical Bonding of Crystalline LnB6 (Ln = La–Lu) and Its Relationship with Ln2B8 Gas-Phase Complexes
Solid-state lanthanide (Ln) borides of the simple LnB6 composition not only exhibit exciting
physical behavior, in particular magnetic properties, but their electronic structure and …
physical behavior, in particular magnetic properties, but their electronic structure and …
Pentavalent lanthanide compounds: formation and characterization of praseodymium (V) oxides
Q Zhang, SX Hu, H Qu, J Su, G Wang… - Angewandte Chemie …, 2016 - Wiley Online Library
The chemistry of lanthanides (Ln= La–Lu) is dominated by the low‐valent+ 3 or+ 2 oxidation
state because of the chemical inertness of the valence 4f electrons. The highest known …
state because of the chemical inertness of the valence 4f electrons. The highest known …
Spectroscopic and electrochemical characterization of a Pr 4+ imidophosphorane complex and the redox chemistry of Nd 3+ and Dy 3+ complexes
The molecular tetravalent oxidation state for praseodymium is observed in solution via
oxidation of the anionic trivalent precursor [K][Pr3+ (NP (1, 2-bis-tBu-diamidoethane)(NEt2)) …
oxidation of the anionic trivalent precursor [K][Pr3+ (NP (1, 2-bis-tBu-diamidoethane)(NEt2)) …
Tetravalent Terbium Chelates: Stability Enhancement and Property Tuning
Coordination chemistry of rare-earth elements has been dominated by the+ 3 oxidation
state. Complexes with higher-valence lanthanide ions are synthetically challenging but are …
state. Complexes with higher-valence lanthanide ions are synthetically challenging but are …
Pentavalent lanthanide nitride-oxides: NPrO and NPrO− complexes with N [triple bond, length as m-dash] Pr triple bonds
The neutral molecule NPrO and its anion NPrO− are produced via co-condensation of laser-
ablated praseodymium atoms with nitric oxide in a solid neon matrix. Combined infrared …
ablated praseodymium atoms with nitric oxide in a solid neon matrix. Combined infrared …
Organolanthanide Complexes Containing Ln–CH3 σ-bonds: Unexpectedly Similar Hydrolysis Rates for Trivalent and Tetravalent Organocerium
Z Shafi, JK Gibson - Inorganic Chemistry, 2023 - ACS Publications
We report the gas-phase preparation, isolation, and reactivity of a series of
organolanthanides featuring the Ln–CH3 bond. The complexes are formed by …
organolanthanides featuring the Ln–CH3 bond. The complexes are formed by …
Is pentavalent Pr (v) feasible in solid CsPrF 6?
The oxidation state (OS) holds significant importance in the field of chemistry and serves as
a crucial parameter for tracking electrons. Lanthanide (Ln) elements predominately exhibit …
a crucial parameter for tracking electrons. Lanthanide (Ln) elements predominately exhibit …
[HTML][HTML] Physicochemical Characterization and Antimicrobial Properties of Lanthanide Nitrates in Dilute Aqueous Solutions
G Kuz'micheva, A Trigub, A Rogachev, A Dorokhov… - Molecules, 2024 - mdpi.com
This work presents the results of studying dilute aqueous solutions of commercial Ln (NO3)
3· x H2O salts with Ln= Ce-Lu using X-ray diffraction (XRD), IR spectroscopy, X-ray …
3· x H2O salts with Ln= Ce-Lu using X-ray diffraction (XRD), IR spectroscopy, X-ray …
On the Highest Oxidation States of Metal Elements in MO4 Molecules (M = Fe, Ru, Os, Hs, Sm, and Pu)
Metal tetraoxygen molecules (MO4, M= Fe, Ru, Os, Hs, Sm, Pu) of all metal atoms M with
eight valence electrons are theoretically studied using density functional and correlated …
eight valence electrons are theoretically studied using density functional and correlated …