Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Alkene functionalization with a single-atom catalyst (SAC) which merges homogeneous and
heterogeneous catalysis is a fascinating route to obtain high-value-added molecules …

Iron‐catalyzed C− H amination is emerging as an attractive and sustainable method to
install amine functionalities into organic compounds. Amination of C (sp3)− H bonds is …

Transition-metal-catalyzed direct C–N bond formation via metal nitrenoid (metal
imido/nitrene complexes) transfer reactions such as C–H bond amination/amidation and …

Enzymes are highly efficient catalysts in Nature that often react with high stereo-, chemo-,
and regioselectivity. Usually, enzymes achieve this selectivity through substrate binding and …

Herein, we study the mechanism of iron-catalyzed direct synthesis of unprotected
aminoethers from olefins by a hydroxyl amine derived reagent using a wide range of …

Reduction of previously reported iminyl radical (ArL) FeCl (• N (C6H4-pt Bu))(2) with
potassium graphite furnished the corresponding high-spin (S= 5/2) imido (ArL) Fe (N (C6H4 …

The redox noninnocence of the TAML scaffold in cobalt-TAML (tetra-amido macrocyclic
ligand) complexes has been under debate since 2006. In this work, we demonstrate with a …

Aziridination has very recently been found to be catalyzed by heme and nonheme Fe
enzymes, opening the way to biotechnological developments. However, its mechanism is …

Ferrate (VI) has the potential to play a key role in future water supplies. Its salts have been
suggested as “green” alternatives to current advanced oxidation and disinfection methods in …