Supramolecular coordination cages for artificial photosynthesis and synthetic photocatalysis

R Ham, CJ Nielsen, S Pullen, JNH Reek - Chemical Reviews, 2023 - ACS Publications
Because sunlight is the most abundant energy source on earth, it has huge potential for
practical applications ranging from sustainable energy supply to light driven chemistry. From …

Redox-active metal–organic frameworks for energy conversion and storage

J Calbo, MJ Golomb, A Walsh - Journal of Materials Chemistry A, 2019 - pubs.rsc.org
Metal–organic frameworks (MOFs) are hybrid solids formed of organic and inorganic
building blocks. While the nature of electron addition, removal, and transport is well known …

Emergent behavior in nanoconfined molecular containers

W Liu, JF Stoddart - Chem, 2021 - cell.com
The expression of biological functions, such as enzyme catalysis, immune response, and
cargo transport in confined nanospaces, with very different physical and chemical …

Functional molecular flasks: new properties and reactions within discrete, self‐assembled hosts

M Yoshizawa, JK Klosterman… - Angewandte Chemie …, 2009 - Wiley Online Library
Insider dealing: Self‐assembled hosts applied as “molecular flasks” can alter and control the
reactivity and properties of molecules encapsulated within their well‐defined, confined …

Molecular engineering of noncovalent dimerization

G Wu, F Li, B Tang, X Zhang - Journal of the American Chemical …, 2022 - ACS Publications
Dimers are probably the simplest model to facilitate the understanding of fundamental
physical and chemical processes that take place in much-expanded systems like …

Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks

LS Xie, EV Alexandrov, G Skorupskii, DM Proserpio… - Chemical …, 2019 - pubs.rsc.org
We report three electrically conductive metal–organic frameworks (MOFs) based on a
tetrathiafulvalene linker and La3+. Depending on the solvent ratios and temperatures used …

High charge mobility in a tetrathiafulvalene-based microporous metal–organic framework

TC Narayan, T Miyakai, S Seki… - Journal of the American …, 2012 - ACS Publications
The tetratopic ligand tetrathiafulvalene-tetrabenzoate (H4TTFTB) is used to synthesize Zn2
(TTFTB), a new metal–organic framework that contains columnar stacks of tetrathiafulvalene …

Stimuli-responsive Pd 2 L 4 metallosupramolecular cages: towards targeted cisplatin drug delivery

JEM Lewis, EL Gavey, SA Cameron, JD Crowley - Chemical Science, 2012 - pubs.rsc.org
Metallosupramolecular cages are an emerging, but as of yet relativity unexplored, drug
delivery vector. Herein we show that discrete dipalladium (II) molecular cages of the formula …

Supramolecular chemistry in water

GV Oshovsky, DN Reinhoudt… - Angewandte Chemie …, 2007 - Wiley Online Library
Supramolecular chemistry in water is a constantly growing research area because
noncovalent interactions in aqueous media are important for obtaining a better …

Recent advances and perspectives on supramolecular radical cages

B Huang, L Mao, X Shi, HB Yang - Chemical Science, 2021 - pubs.rsc.org
Supramolecular radical chemistry has been emerging as a cutting-edge interdisciplinary
field of traditional supramolecular chemistry and radical chemistry in recent years. The …